tert-Butoxy bis(dimethylamino)methane
Suppliers
Names
[ CAS No. ]:
5815-08-7
[ Name ]:
tert-Butoxy bis(dimethylamino)methane
[Synonym ]:
Bredereck’s reagent
Methanediamine, 1-(1,1-dimethylethoxy)-N,N,N',N'-tetramethyl-
tert-Butoxy bis(dimethylamino)methane
EINECS 227-383-9
tert-butoxybis(dimethylamino)methane
Brederick’s reagent
MFCD00042858
N,N,N',N'-Tetramethyl-1-[(2-methyl-2-propanyl)oxy]methanediamine
1-tert-Butoxy-N,N,N',N'-tetramethylmethanediamine
EINECS 227-383-9
Chemical & Physical Properties
[ Density]:
0.9±0.1 g/cm3
[ Boiling Point ]:
176.9±20.0 °C at 760 mmHg
[ Molecular Formula ]:
C9H22N2O
[ Molecular Weight ]:
174.284
[ Flash Point ]:
35.2±19.0 °C
[ Exact Mass ]:
174.173218
[ PSA ]:
15.71000
[ LogP ]:
2.14
[ Vapour Pressure ]:
1.1±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.446
[ Storage condition ]:
Freezer (-20°C)
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R10;R36/37/38
[ Safety Phrases ]:
S26
[ RIDADR ]:
UN 1993 3/PG 3
[ WGK Germany ]:
3
[ Packaging Group ]:
III
[ Hazard Class ]:
3
[ HS Code ]:
2922199090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2922199090
[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Chem. Biol. 18 , 67-76, (2011)
There is a growing recognition of the importance of protein kinases in the control of alternative splicing. To define the underlying regulatory mechanisms, highly selective inhibitors are needed. Here...
Angew. Chem. Int. Ed. Engl. 48(29) , 5366-8, (2009)
Ringing the changes: The total synthesis of the title compound centers around a novel strategy that employs a nickel(0)-phosphine complex and triethyl borane in an efficient closure of a 14-membered r...
Arch. Pharm. (Weinheim) 339(12) , 677-9, (2006)
The one-pot reaction of 4-benzylpyridine-3-carbonitrile with Bredereck's reagent and subsequent treatment with either glacial acetic acid and sulfuric acid or ammonium acetate provided the new bioacti...