1-Bromo-2,4-dimethylbenzene

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Names

[ CAS No. ]:
583-70-0

[ Name ]:
1-Bromo-2,4-dimethylbenzene

[Synonym ]:
MFCD00000071
EINECS 209-517-8
Benzene, 1-bromo-2,4-dimethyl-
1-Bromo-2,4-dimethylbenzene
4-Bromo-1,3-dimethylbenzene

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
207.2±9.0 °C at 760 mmHg

[ Melting Point ]:
-1ºC

[ Molecular Formula ]:
C8H9Br

[ Molecular Weight ]:
185.061

[ Flash Point ]:
81.6±13.1 °C

[ Exact Mass ]:
183.988754

[ LogP ]:
3.91

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.544

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ WGK Germany ]:
3

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • m-Xylene
  • 5-bromo-6,8-dimethyl-2,3-dihydrobenzo[b][1,4]dithiine
  • (2,4-dimethylphenyl) trifluoromethanesulfonate
  • 2,4-Xylidine
  • Methyl fluoride
  • 4-Bromotoluene
  • 2-Bromotoluene
  • 2,6-Dimethylbromobenzene

DownStream

  • (2,4-DICHLOROBENZYL)METHYLAMINEHYDROCHLORIDE
  • 1-Bromo-3,5-dimethylbenzene
  • 2,6-Dimethylbromobenzene
  • m-Xylene
  • Tris(2,5-dimethylphenyl)phosphine
  • 1-bromo-2,4-dimethyl-5-methylsulfonylbenzene
  • 2-(2,4-dimethylphenyl)benzoic acid
  • 2,4-Dimethylbenzoic acid
  • 2,4-dimethylphenylmagnesium bromide
  • 1-bromo-4-(bromomethyl)-2-methylbenzene

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Gold (I)-catalyzed direct C-H arylation of pyrazine and pyridine with aryl bromides. Li M and Hua R.

Tetrahedron Lett. 50(13) , 1478-81, (2009)

Transformation of aromatic bromides into aromatic nitriles via formations of grignard reagents and their DMF adducts. Ishii G, et al.

Tetrahedron Lett. 52(18) , 2404-6, (2011)


More Articles

Related Compounds

  • 1-bromo-2-(tosyloxy)-3,4-dimethylbenzene
  • 1-Bromo-2-fluoro-3,5-dimethylbenzene
  • 1-Bromo-2,4-difluorobenzene
  • 1-BROMO-2,4-DIFLUORO-5-NITROBENZENE
  • 1-bromo-2,4-diisopropyl-benzene
  • 1-bromo-2-[(4-methylphenoxy)methyl]benzene
  • 1-(2,2-Dimethylthiolan-3-yl)propan-2-one
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 2-amino-2-(2,2-dimethyl-3,4-dihydro-2H-1-benzopyran-6-yl)propan-1-ol
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 2-[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanamido]-2-(methoxymethyl)butanoic acid
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • ethyl 1-methyl-4-(piperidin-3-yl)-1H-pyrazole-3-carboxylate