4-Bromo-N,N-dimethylaniline

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Names

[ CAS No. ]:
586-77-6

[ Name ]:
4-Bromo-N,N-dimethylaniline

[Synonym ]:
N-(4-bromophenyl)-N,N-dimethylamine
p-(Dimethylamino)phenyl bromide
N,N-Dimethyl-p-bromoaniline
Benzenamine, 4-bromo-N,N-dimethyl-
Benzenamine,4-bromo-N,N-dimethyl
EINECS 209-582-2
4-Bromo-N,N-dimethylbenzenamine
4-N,N-dimethylaminobromobenzene
MFCD00000093
(4-bromophenyl)dimethylamine
N,N-Dimethyl-4-bromoaniline
1-bromo-4-dimethylaminobenzene
p-Bromo-N,N-dimethylaniline
N,N-(dimethylamino)-4-bromobenzene
p-Dimethylaminobromobenzene
4-Bromo-N,N-dimethylaniline
4-bromo-N,N-dimethyl-aniline
(4-bromo-phenyl)-dimethylamine
4-dimethylamino-1-bromobenzene
4-Dimethylaminobromobenzene

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
264.0±0.0 °C at 760 mmHg

[ Melting Point ]:
52-54 °C(lit.)

[ Molecular Formula ]:
C8H10BrN

[ Molecular Weight ]:
200.076

[ Flash Point ]:
104.7±19.8 °C

[ Exact Mass ]:
198.999649

[ PSA ]:
3.24000

[ LogP ]:
3.34

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.587

[ Stability ]:
Stable. Incompatible with oxidizing agents, acids, metals.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BW9300000
CHEMICAL NAME :
Aniline, 4-bromo-N,N-dimethyl-
CAS REGISTRY NUMBER :
586-77-6
LAST UPDATED :
199709
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C8-H10-Br-N
MOLECULAR WEIGHT :
200.10
WISWESSER LINE NOTATION :
ER DN1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 90,260,1947

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R33

[ Safety Phrases ]:
S26-S36-S45-S37-S28A

[ RIDADR ]:
2811

[ WGK Germany ]:
3

[ RTECS ]:
BW9300000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2921499090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • N,N-Dimethylaniline
  • Formaldehyde
  • 4-Bromoaniline
  • methyl iodide
  • Diisopropyl azodicarboxylate
  • dichloro(4-N,N-dimethylaminophenyl)phosphine
  • Methanol
  • Dimethyl sulfoxide
  • 4-(Dimethylamino)phenylboronic acid
  • Benzenemethanol,4-(dimethylamino)-a-phenyl-

DownStream

  • 4-(6-METHOXYBENZO[D]THIAZOL-2-YL)-N,N-DIMETHYLANILINE
  • N,N-dimethyl-4-methyltellanylaniline
  • Benzenamine,4,4',4''-phosphinidynetris[N,N-dimethyl-
  • 4-[[4-(dimethylamino)phenyl]-phenylphosphanyl]-N,N-dimethylaniline
  • N-methyl-N-phenyl-butanamide
  • Yellow pyoctanine
  • Bromine
  • N,N,N',N'-TETRAMETHYLBENZIDINE
  • 4,4'-Difluorobiphenyl

Customs

[ HS Code ]: 2921420090

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases.

Dalton Trans. 44 , 9847-59, (2015)

Utilization of dioxygen as the terminal oxidant at ambient temperature is always a challenge in redox chemistry, because it is hard to oxidize a stable redox metal ion like iron(III) to its high oxida...

Single drop microextraction or solid phase microextraction-gas chromatography-mass spectrometry for the determination of iodine in pharmaceuticals, iodized salt, milk powder and vegetables involving conversion into 4-iodo-N,N-dimethylaniline.

J. Chromatogr. A. 1023(1) , 33-9, (2004)

A rapid sequence of oxidation and iodination using 2-iodosobenzoate as an oxidizing agent and N,N-dimethylaniline as an iodine scavenger at pH 6.4, when 4-iodo-N,N-dimethylaniline is formed, has been ...


More Articles

Related Compounds

  • 4-Bromo-N,N-dimethylaniline
  • 4-bromo-N,N-dimethylaniline oxide
  • 2-methyl-4-bromo-N,N-dimethylaniline
  • 4-BROMO-N,N-DIMETHYL-2-FLUOROANILINE
  • 4-Bromo-N,N-dimethyl-2-nitroaniline
  • 4-Bromo-2-chloro-N,N-dimethylaniline
  • benzyl N-{6-bromo-[1,2,4]triazolo[1,5-a]pyrimidin-2-yl}carbamate
  • benzyl N-[(3-aminophenyl)(methyl)oxo-lambda6-sulfanylidene]carbamate
  • benzyl N-[5-(1-hydroxycyclobutyl)-1,3-thiazol-2-yl]carbamate
  • benzyl N-(3,6-dichloropyridazin-4-yl)-N-methylcarbamate
  • 2-Fluoro-1-methoxy-4-[3-(1-methylcyclopropyl)phenyl]benzene
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}(2-nitrophenyl)amino)-2,2-dimethylpropanoic acid
  • Ethyl 2-{[(benzyloxy)carbonyl]amino}-4-(4-bromophenyl)-1,3-thiazole-5-carboxylate
  • 1-benzyl 4-tert-butyl (2R)-6-bromo-2-methyl-1,2,3,4-tetrahydroquinoxaline-1,4-dicarboxylate
  • 1-benzyl 4-tert-butyl 9-bromo-2,3,4,5-tetrahydro-1H-1,4-benzodiazepine-1,4-dicarboxylate
  • 2-[ethyl({[(9H-fluoren-9-yl)methoxy]carbonyl})amino]-4-(trifluoromethyl)-1,3-thiazole-5-carboxylic acid
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