DIETHYL CHLOROPHOSPHITE

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Names

[ CAS No. ]:
589-57-1

[ Name ]:
DIETHYL CHLOROPHOSPHITE

[Synonym ]:
MFCD00009074
chloro(diethoxy)phosphane
EINECS 209-652-2

Chemical & Physical Properties

[ Density]:
1.089 g/mL at 20 °C(lit.)

[ Boiling Point ]:
153-155 °C(lit.)

[ Molecular Formula ]:
C4H10ClO2P

[ Molecular Weight ]:
156.54800

[ Flash Point ]:
34 °F

[ Exact Mass ]:
156.01100

[ PSA ]:
32.05000

[ LogP ]:
2.52510

[ Index of Refraction ]:
n20/D 1.434(lit.)

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H314-H335

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P261-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Highlyflammable;C:Corrosive;

[ Risk Phrases ]:
R11;R34

[ Safety Phrases ]:
S16-S26-S36/37/39-S45-S7/8

[ RIDADR ]:
UN 2924 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Triethyl phosphite
  • Ethyl phosphorodichloridite
  • Ethanol
  • (4,6-dimethylpyrimidin-2-yl) diethyl phosphite
  • Phosphorocyanidous acid diethyl ester
  • 1,3,2-Diazaphosphol-4-ene, 2-ethoxy-1,3-dibutyl-4,5-dimethyl-
  • Hexamethylphosphoramide
  • Phosphorochloridocyanidous acid, ethyl ester
  • diethyl butyl(2-methylprop-1-en-1-yl)phosphoramidite
  • Acetyl chloride

DownStream

  • 2-diethoxyphosphorylcyclohexan-1-one
  • diethoxyphosphanyl dimethyl phosphate
  • diethoxyphosphanyl ethyl methyl phosphate
  • Triethyl 2-phosphonopropionate
  • methyl oxalyl chloride
  • Dimethyl oxalate
  • monochloroethane
  • methyl 2-chloro-2-(dichlorophosphorylmethoxy)acetate
  • methyl 2-chloro-2-(chloro(methoxy)phosphoryl)-2-methoxyacetate
  • ethyl [chloromethoxy(methoxycarbonyl)methyl]phosphonochloridate

Related Compounds

  • diethyl (4-methoxyphenylthio)methylphosphonate
  • diethyl N-methylaminomethylphosphonate
  • diethyl 2-(1-ethylsulfanyl-2-methylpropyl)propanedioate
  • diethyl 2-benzyl-2-pentylpropanedioate
  • Diethyl-(trimethylsilylamido)-phosphit
  • DIETHYL (1-HYDROXYETHYL)PHOSPHONATE
  • 1-[2-(Benzyloxy)-5-bromo-3,4-dimethylphenyl]ethan-1-one
  • N-(2-Hydroxyethyl)-2-(methylamino)-4-(trifluoromethyl)benzamide
  • Tert-butyl 3-{1-[3-(benzyloxy)phenyl]-1-hydroxyethyl}piperidine-1-carboxylate
  • Tert-butyl 3-(3-phenylmethoxybenzoyl)piperidine-1-carboxylate
  • 1-(1-Methylpiperidin-3-yl)-1-(3-phenylmethoxyphenyl)ethanol
  • ethyl [N'-(2-ethoxy-2-oxoacetyl)hydrazinecarbonyl]formate
  • 1-Benzyl-2,3,4,5-tetrahydro-1-benzazepine-2-carboxamide
  • 2-O-Tert-butyl 3-O-ethyl 1,3,4,9-tetrahydropyrido[3,4-b]indole-2,3-dicarboxylate
  • Tert-butyl 3-(hydroxymethyl)-1,3,4,9-tetrahydropyrido[3,4-b]indole-2-carboxylate
  • Tert-butyl 3-(methylsulfonyloxymethyl)-1,3,4,9-tetrahydropyrido[3,4-b]indole-2-carboxylate
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