Bromoacetonitrile

Suppliers

Names

[ CAS No. ]:
590-17-0

[ Name ]:
Bromoacetonitrile

[Synonym ]:
EINECS 209-672-1
MFCD00001884
2-bromoacetonitrile
Acetonitrile, 2-bromo-
Bromoacetonitrile

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
154.5±0.0 °C at 760 mmHg

[ Melting Point ]:
-36ºC

[ Molecular Formula ]:
C2H2BrN

[ Molecular Weight ]:
119.948

[ Flash Point ]:
24.3±19.8 °C

[ Exact Mass ]:
118.937057

[ PSA ]:
23.79000

[ LogP ]:
0.25

[ Vapour Pressure ]:
3.2±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.469

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AL7970000
CHEMICAL NAME :
Acetonitrile, bromo-
CAS REGISTRY NUMBER :
590-17-0
BEILSTEIN REFERENCE NO. :
0956569
LAST UPDATED :
199612
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C2-H2-Br-N
MOLECULAR WEIGHT :
119.96

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Micronucleus test

MUTATION DATA

TEST SYSTEM :
Rodent - rat
DOSE/DURATION :
19350 ug/kg
REFERENCE :
TOXID9 Toxicologist. (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway, Akron, OH 44311) V.1- 1981- Volume(issue)/page/year: 13,220,1993

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R23/24/25;R36/37/38

[ Safety Phrases ]:
S26-S36-S45-S24/25

[ RIDADR ]:
UN 3276 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
AL7970000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2926909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Iodoacetonitrile
  • 2-chloroacetonitrile
  • Acetonitrile
  • 2-Bromoacetamide
  • 1-Piperidinylacetonitrile
  • Cyanogen bromide
  • Acetonitrile,2-(dipropylamino)-
  • Acetonitrile,2-[bis(2-methylpropyl)amino]-
  • 1-Bromo-2,4-difluorobenzene
  • 2-Bromo-1,3-difluorobenzene

DownStream

  • 1,1-Di(1H-imidazol-1-yl)methanimine
  • ethyl 2-(cyanomethoxy)acetate
  • (Biphenyl-2-yloxy)-acetonitrile
  • (4-Bromophenoxy)acetonitrile
  • 3-(2-Methylphenyl)-3-oxopropanenitrile
  • (2-Methylphenoxy)acetonitrile
  • 3-(4-Methoxyphenyl)-3-oxopropanenitrile
  • 2-CHLOROPHENOXYACETONITRILE
  • BENZENEPROPANENITRILE, 4-CHLORO-
  • 3-(2-Bromophenyl)-3-oxopropanenitrile

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis, characterization, and energetic properties of salts of the 1-cyanomethyl-1,1-dimethylhydrazinium cation.

Chem. Asian J. 7(5) , 1085-95, (2012)

1,1-Dimethylhydrazine can be readily alkylated with bromoacetonitrile to form 1-cyanomethyl-1,1-dimethylhydrazinium bromide ([(CH(3))(2)N(CH(2)CN)NH(2)]Br, 1). The metathesis reaction of compound 1 le...


More Articles

Related Compounds

  • Bromoacetonitrile
  • methyl bromoacetonitrile
  • (4-methylphenyl)bromoacetonitrile
  • 2-((2Z,5Z)-bicyclo[5.4.1]dodeca-1(11),2,5,7,9-pentaen-4-ylidene)-2-bromoacetonitrile