1-Bromo-3-iodobenzene

Names

[ CAS No. ]:
591-18-4

[ Name ]:
1-Bromo-3-iodobenzene

[Synonym ]:
m-Bromoiodobenzene
EINECS 209-703-9
3-iodobromobenzene
3-Bromoiodobenzene
3-bromo-1-iodobenzene
Benzene,1-bromo-3-iodo
MFCD00001043
1-iodo-3-bromobenzene

Chemical & Physical Properties

[ Density]:
2.2±0.1 g/cm3

[ Boiling Point ]:
239.6±0.0 °C at 760 mmHg

[ Melting Point ]:
−9.3-−9 °C(lit.)

[ Molecular Formula ]:
C₆H₄BrI

[ Molecular Weight ]:
282.90

[ Flash Point ]:
105.3±22.6 °C

[ Exact Mass ]:
281.854095

[ LogP ]:
4.03

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.655

[ Water Solubility ]:
insoluble

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Precursor & DownStream

Precursor

DownStream

tert-butyl 4-(3-bromophenyl)piperazine-1-carboxylate
3-Bromothioanisole
1-Bromo-3-(4-fluorophenoxy)benzene
2-(3-Bromophenyl)pyridine
9-(3-Bromophenyl)-9H-carbazole
1-ALLYL-3-BROMOBENZENE
1-bromo-3-[(4-fluorophenyl)methyl]benzene
1-Azido-3-bromobenzene
3-Chlorobenzoic Acid
(3-Bromophenyl)(4-fluorophenyl)Methanol

Articles

Asymmetric Au-catalyzed cycloisomerization of 1,6-enynes: An entry to bicyclo[4.1.0]heptene.

Beilstein J. Org. Chem. 7 , 1021-9, (2011)

A comprehensive study on the asymmetric gold-catalyzed cycloisomerization reaction of heteroatom tethered 1,6-enynes is described. The cycloisomerization reactions were conducted in the presence of th...

Efficient access to perfluoroalkylated aryl compounds by Heck reaction. Darses S, et al.

European J. Org. Chem. 2001(6) , 1121-28, (2001)

1-Bromo-3-fluoro-5-iodobenzene
1-Bromo-3-ethoxy-2-iodobenzene
1-Bromo-3-fluoro-2-iodobenzene
1-Bromo-3-chloro-5-iodobenzene
1-Bromo-3-(chloromethyl)-5-iodobenzene
1-Bromo-3-fluoro-4-iodobenzene
rac-(1R,2R)-2-(2-bromo-5-hydroxy-4-methoxyphenyl)cyclopropane-1-carboxylic acid
5-(5-Formylfuran-2-yl)-4-methylfuran-2-carboxylic acid
methyl 4-isocyanato-1-methyl-1H-pyrrole-2-carboxylate
Methyl 3-amino-2-(3,5-dichloropyridin-4-yl)propanoate
3-[(Benzyloxy)carbonyl]-5-methyl-1,3-oxazolidine-5-carboxylic acid
2-[1-({[(Tert-butoxy)carbonyl]amino}oxy)-4-methylcyclohexyl]acetic acid
4-(5-formylthiophen-3-yl)-1H-pyrrole-2-carboxylic acid
Methyl 2-amino-3-methyl-3-(5-methylpyrazin-2-yl)butanoate
2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-5-methanesulfonylbenzoic acid
4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-(5-methyl-1H-1,2,3,4-tetrazol-1-yl)benzoic acid

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