Phenyllithium

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Names

[ CAS No. ]:
591-51-5

[ Name ]:
Phenyllithium

[Synonym ]:
Phenyllithium
Phenyl lithium
LITHIUMPHENYL
Lithiobenzene
EINECS 209-720-1
phenylllithium
MFCD00014254
PhLi
PHENYLLITHIUM DIBUTYL
phenyllitihium
PHENYLLITHIUM SOLUTION IN DIBUTYLETHER
MFCD06200758
Lithium, phenyl-
phenyl-lithium

Chemical & Physical Properties

[ Density]:
0.835 g/mL at 25 °C

[ Boiling Point ]:
140-143 °C

[ Molecular Formula ]:
C₆H₅Li

[ Molecular Weight ]:
84.045

[ Flash Point ]:
20 °C

[ Exact Mass ]:
84.055130

[ LogP ]:
1.48680

[ Storage condition ]:
2-8°C

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H250-H314-H335-H412

[ Precautionary Statements ]:
P210-P231-P280-P305 + P351 + P338-P370 + P378-P422

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R14;R35;R52/53

[ Safety Phrases ]:
S26-S36/37/39-S45-S61-S62-S60-S43-S16-S6

[ RIDADR ]:
UN 3392 4.2/PG 1

[ WGK Germany ]:
2

[ Packaging Group ]:
II

[ Hazard Class ]:
4.3

Synthetic Route

Click to get detail synthetic route

Articles

Organo-palladium(II) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions.

Dalton Trans. 44(16) , 7230-41, (2015)

The 2-(2′-aniline)-6-imine-pyridines, 2-(C6H4-2′-NH2)-6-(CMe=NAr)C5H3N (Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)), have been synthesised via sequential Stille cross-coupling, deprotection and cond...