(Chloromethyl)cyclopropane

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Names

[ CAS No. ]:
5911-08-0

[ Name ]:
(Chloromethyl)cyclopropane

[Synonym ]:
Cyclopropylmethyl Chloride, Pract.
cyclopropylmethyl chloride
MFCD00001307
chloromethylcyclopropane
(Chloromethyl)cyclopropane
Cyclopropane, (chloromethyl)-
EINECS 227-632-1

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
87.6±9.0 °C at 760 mmHg

[ Melting Point ]:
-91°C

[ Molecular Formula ]:
C4H7Cl

[ Molecular Weight ]:
90.551

[ Flash Point ]:
-1.7±0.0 °C

[ Exact Mass ]:
90.023628

[ LogP ]:
1.87

[ Vapour Pressure ]:
71.1±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.458

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S26-S36/37/39

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
29035990

Synthetic Route

Precursor & DownStream

Precursor

  • Cyclopropyl carbinol
  • Carbon tetrachloride
  • cyclopropylmethanol,phosphorous acid
  • methylcyclopropane
  • 3-cyclopropylmethoxy-3-chlorodiaziridine
  • cyclopropylcarbinol hypochlorite
  • cyclobutoxychlorocarbene
  • 3,4-dichlorobut-1-ene
  • Cyclobutanol

DownStream

  • 4-Brombut-1-en
  • Bromocyclobutane
  • (Bromomethyl)cyclopropane
  • (HYDROXYMETHYL)-2-PYRROLIDINONE
  • 4-Chloro-1-Butene
  • Chlorocyclobutane
  • acetic acid,cyclopropylmethanol
  • cyclobutyl acetate
  • Cyclopropyl carbinol

Customs

[ HS Code ]: 2903890090

[ Summary ]:
2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Easy selective generation of (lithiomethyl) cyclopropane or homoallyllithium by a chlorine-lithium exchange. Pastor IM, et al.

Tetrahedron Lett. 49(48) , 6870-72, (2008)

Unexpected reactions of an isolable dialkylsilylene with Haloalkanes. Ishida S, et al.

Chem. Lett. 11 , 1102-1103, (2001)


More Articles


Related Compounds

  • 1,1-dibromo-2-(chloromethyl)cyclopropane
  • 1,1-dichloro-2-(chloromethyl)cyclopropane
  • 1,1,2-trichloro-2-(chloromethyl)cyclopropane
  • 1,1-DICHLORO-2,3-DI(CHLOROMETHYL)CYCLOPROPANE
  • 1,1-Dibromo-2,2-bis(chloromethyl)cyclopropane
  • 2-(Chloromethyl)cyclopropane-1-carboxylic acid