Methyl 2-(dimethoxyphosphoryl)acetate

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Names

[ CAS No. ]:
5927-18-4

[ Name ]:
Methyl 2-(dimethoxyphosphoryl)acetate

[Synonym ]:
Acetic acid, 2-(dimethoxyphosphinyl)-, methyl ester
trimethyl phosphorylacetate
Trimethylphosphoroacetate
TRIMETHYL PHOPHONOACETATE
Trimethylphosphonoacetate
dimethyl methoxycarbonylmethanephosphonate
Methyl (dimethoxyphosphoryl)acetate
TMPA
METHYL DIMETHYLPHOSPHONOACETATE
EINECS 227-663-0
TRIMETHYL PHOSPHONACETATE
dimethyl carbomethoxymethylphosphonate
PHOSPHONOACETIC ACID TRIMETHYL ESTER
trimethylacetyl phosphate
MFCD00008452

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
311.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H11O5P

[ Molecular Weight ]:
182.112

[ Flash Point ]:
109.7±42.9 °C

[ Exact Mass ]:
182.034409

[ PSA ]:
71.64000

[ LogP ]:
-0.68

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.408

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29310095

Synthetic Route

Precursor & DownStream

Precursor

  • Methanol
  • Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate
  • METHYL DIAZOACETATE
  • Dimethyl phosphonate
  • Methyl bromoacetate
  • Trimethyl phosphite
  • methyl chloroacetate
  • ETHYL 2-(DIPHENOXYPHOSPHORYL)ACETATE
  • Acetic acid,2-phosphono-

DownStream

  • methyl farnesoate
  • 2-Hydroxy-4-(trifluoromethyl)pyridine
  • Benzyl (dimethoxyphosphoryl)acetate
  • 2-Pentenoic Acid, 4-[[)1,1-Dimethylethoxy)Carbonyl]amino]-, (2E,4s)-(9CI)
  • 1-BOC-4-(4-METHOXY-4-OXO-2-BUTENYL)PIPERIDINE
  • methyl 3-(4-methoxyphenyl)but-2-enoate
  • methyl 2-bromo-3-methylbut-2-enoate
  • Methyl 3-methyl-2-butenoate
  • 2-Propenoic acid,3-(9-anthracenyl)-, methyl ester, (2E)-

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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Epidemiological studies consistently find that diets rich in whole-grain (WG) cereals lead to decreased risk of disease compared with refined grain (RG)-based diets. Aside from a greater amount of fib...

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Arch. Biochem. Biophys. 223(2) , 360-8, (1983)

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Related Compounds

  • methyl 2-(dimethoxyphosphoryl)-2-phenylacetate
  • Methyl 2-(benzyloxycarbonylamino)-2-dimethoxyphosphoryl-acetate
  • methyl 2-(tert-butyldimethylsiloxy)-2-(dimethoxyphosphoryl)acetate
  • methyl 2-(tert-butoxycarbonyl)-2-(dimethoxyphosphoryl)-acetate
  • Methyl 2-[(S)-2-tert-butoxycarbonylamino-4-methylpentanoylamino]-2-(dimethoxyphosphoryl)acetate
  • Methyl 2-(N-Benzoylamino)-2-(dimethoxyphosphinyl)ethanoate