Chloroiodomethane

Names

[ CAS No. ]:
593-71-5

[ Name ]:
Chloroiodomethane

[Synonym ]:
Chloro(iodo)methane
EINECS 209-804-8
Methane, chloroiodo-
Chloroiodomethane
MFCD00001078

Chemical & Physical Properties

[ Density]:
2.3±0.1 g/cm3

[ Boiling Point ]:
102.2±8.0 °C at 760 mmHg

[ Molecular Formula ]:
CH₂ClI

[ Molecular Weight ]:
176.384

[ Flash Point ]:
15.6±18.4 °C

[ Exact Mass ]:
175.888962

[ LogP ]:
1.56

[ Vapour Pressure ]:
39.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.565

[ Storage condition ]:
0-6°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S24/25-S23

[ RIDADR ]:
UN2810

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29034980

Precursor & DownStream

Precursor

Dichloromethane
Diiodomethane
methyl iodide
Bromochloromethane
chloro(chloromethyl)mercury
benzyl-chloromethyl selenide
Hydrogen iodide
iodomethane

DownStream

chloromethyl butyrate
1,2-Dibromobutane
N-(1-adamantyl)-2-chloroacetamide
3-Phenyl-1-propylboronic acid pinacol ester
Eschenmoser's reagent
2-Chloro-N-(2-chloro-5-(trifluoromethyl)phenyl)acetamide
1,3-Dichloroacetone
Styrene oxide
Methylbenzylalcohol

Customs

[ HS Code ]: 29034980

Articles

Formation and relaxation dynamics of iso-CH2Cl-I in cryogenic matrices.

J. Chem. Phys. 135(11) , 114503, (2011)

Photolysis of chloroiodomethane (CH(2)ClI) in cryogenic matrices followed by recombination of the nascent radical pair produces an isomer (CH(2)Cl-I) that features a halogen-halogen (Cl-I) bond. Using...