dimethylmercury

Suppliers

Names

[ CAS No. ]:
593-74-8

[ Name ]:
dimethylmercury

[Synonym ]:
Dimethyl-quecksilber
MFCD00014845
Mercury,dimethyl
DIMETHYLMERCURY
methyl-Hg-methyl
diemthylmercury
dimethylmercure
EINECS 209-805-3
dimethyl-mercury
UNII-C60TQU15XY

Chemical & Physical Properties

[ Density]:
2.961 g/mL at 25ºC(lit.)

[ Boiling Point ]:
93-94ºC(lit.)

[ Melting Point ]:
-43ºC(lit.)

[ Molecular Formula ]:
C2H6Hg

[ Molecular Weight ]:
230.65900

[ Flash Point ]:
42ºC

[ Exact Mass ]:
232.01800

[ LogP ]:
1.16510

[ Index of Refraction ]:
n20/D 1.543(lit.)

[ Storage condition ]:
Flammables area

[ Stability ]:
Stable. Highly flammable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
insoluble H2O; soluble ether, alcohol [MER06]

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OW3010000
CHEMICAL NAME :
Mercury, dimethyl
CAS REGISTRY NUMBER :
593-74-8
BEILSTEIN REFERENCE NO. :
3600205
LAST UPDATED :
199712
DATA ITEMS CITED :
32
MOLECULAR FORMULA :
C2-H6-Hg
MOLECULAR WEIGHT :
230.67
WISWESSER LINE NOTATION :
1-HG-1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
40 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 290,281,1993 *** REVIEWS *** ACGIH TLV-TWA 0.01 mg(Hg)/m3; STEL 0.03 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 58,239,1993 IARC Cancer Review:Group 2B IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 58,239,1993 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.001 ppm (0.01 mg(Hg)/m3) DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,22,1973 OSHA PEL (Gen Indu):8H TWA 0.01 mg(Hg)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.01 mg(Hg)/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.01 mg(Hg)/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.01 mg(Hg)/m3 (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.01 mg(Hg)/m3;STEL 0.03 mg(Hg)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.01 mg(Hg)/m3;STEL 0.03 mg(Hg)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.01 mg(Hg)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.01 mg(Hg)/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.01 mg(Hg)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.01 mg(Hg)/m3;STEL 0.02 mg(Hg)/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 0.01 mg(Hg)/m3 JAN 1993 OEL-SWEDEN:TWA 0.01 mg(Hg)/m3;Skin JAN 1993 OEL-THAILAND:TWA 0.01 mg(Hg)/m3;STEL 0.04 mg(Hg)/m3 JAN 1993 OEL-TURKEY:TWA 0.01 mg(Hg)/m3;Skin JAN 1993 OEL-UNITED KINGDOM:TWA 0.01 mg(Hg)/m3;STEL 0.03 mg(Hg)/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Safety Information

[ Hazard Codes ]:
T+,N

[ Risk Phrases ]:
R26/27/28

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 3383

[ WGK Germany ]:
3

[ RTECS ]:
OW3010000

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

Synthetic Route

Precursor & DownStream

Precursor

  • methyl
  • Diphenylmercury
  • Trimethyl-Gallium
  • METHYLMAGNESIUM IODIDE
  • methyl iodide
  • aluminum carbide
  • Bis[trifluoromethyl]mercury
  • tetramethyllead
  • Methyl bromide
  • METHYLMERCURY(II) CHLORIDE

DownStream

  • methyl mercuric acetate
  • Tritanol
  • Peroxide,bis(triphenylmethyl) (9CI)
  • METHYLLITHIUM
  • diethylmercury
  • METHYLSELENOCYANATE
  • 1-Butene
  • cis-2-butene
  • 2-Methylbut-2-ene

Related Compounds

  • 4-(5-Chloro-1H-benzo[d][1,2,3]triazol-1-yl)tetrahydro-2H-thiopyran 1,1-dioxide
  • 1-(2-cyclopropylethyl)-1H-1,2,3-benzotriazol-6-ol
  • 4-Ethyl-3-(2-methylprop-2-en-1-yl)cyclohexan-1-amine
  • 4,4-Dimethyl-3-[(1,2-thiazol-5-yl)methyl]cyclohexan-1-amine
  • 5-(2-Methylbutyl)-1,2,3,6-tetrahydropyridin-3-amine
  • 5-(3,5-Difluorophenyl)-1,2,3,6-tetrahydropyridin-3-amine
  • 2-Methyl-9-oxa-12-azadispiro[4.0.5^{6}.3^{5}]tetradecan-13-one
  • 7,7-Diethyl-2,6-dioxa-8-azaspiro[4.5]decane
  • 1-[2-(4-Bromofuran-2-yl)ethyl]cyclopropan-1-ol
  • 4'-(Oct-1-yn-1-yl)-[1,1'-biphenyl]-4-ol
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