trimethylarsine

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Names

[ CAS No. ]:
593-88-4

[ Name ]:
trimethylarsine

[Synonym ]:
AsMe3
trimethylarsane
Arsine,trimethyl
EINECS 209-815-8
Gosio gas
Trimethylarsenic
Trimethylarsine

Chemical & Physical Properties

[ Boiling Point ]:
53.8ºC at 760 mmHg

[ Melting Point ]:
-87.3ºC

[ Molecular Formula ]:
C3H9As

[ Molecular Weight ]:
120.02500

[ Flash Point ]:
100ºC

[ Exact Mass ]:
119.99200

[ LogP ]:
1.37060

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CH8800000
CHEMICAL NAME :
Arsine, trimethyl-
CAS REGISTRY NUMBER :
593-88-4
BEILSTEIN REFERENCE NO. :
1730780
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C3-H9-As

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
7870 mg/kg
TOXIC EFFECTS :
Blood - other changes
REFERENCE :
FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 14,399,1990
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
20500 ppm/4H
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - tremor Behavioral - ataxia
REFERENCE :
TOXID9 Toxicologist. (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway, Akron, OH 44311) V.1- 1981- Volume(issue)/page/year: 3,24,1983

Safety Information

[ Hazard Codes ]:
T: Toxic;N: Dangerous for the environment;T: Toxic;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S9;S23;S28;S45;S60;S61

[ RIDADR ]:
UN 1992

[ RTECS ]:
CH8800000

[ Packaging Group ]:
I

[ Hazard Class ]:
4.2

Synthetic Route

Precursor & DownStream

Precursor

  • trimethylaluminum
  • METHYLMAGNESIUM IODIDE
  • Dimethylzinc
  • Dimethyliodoarsine
  • Methanol
  • Potassium acetate
  • dimethylarsanyloxy(dimethyl)arsane
  • Arsonium, tetramethyl-,iodide (8CI,9CI)
  • methyl iodide
  • Methylarsonous diiodide

DownStream

  • trimethylarsane oxide
  • Cacodylic acid
  • Arsonium, tetramethyl-,iodide (8CI,9CI)
  • diiodo(trimethyl)-λ5-arsane
  • methyl
  • ethane
  • dimethylarsenic
  • methylarsenic
  • Arsonium,(2-hydroxyethyl)trimethyl-, bromide (1:1)
  • 2-hydroxyethyl(trimethyl)arsanium,chloride

Related Compounds

  • trimethylarsine oxide
  • diiodotrimethylarsine
  • trimethylarsine sulphide
  • Trimethylarsine selenide
  • Gold,chloro(trimethylarsine)
  • Mercury,dichloro(trimethylarsine)