4-Amino-2,6-dichlorophenol

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Names

[ Name ]:
4-Amino-2,6-dichlorophenol

[Synonym ]:
3,5-Dichloro-4-hydroxyaniline
Phenol,4-amino-2,6-dichloro
MFCD00007875
4-amino-2,6-dichloro-phenol
2,6-dichloro-4-amino-phenol
4-Amino-2,6-dichlorophenol
4-Amino-2,6-dichlor-phenol
2,6-Dichloro-p-aminophenol
EINECS 227-671-4
Phenol, 4-amino-2,6-dichloro-

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
303.6±42.0 °C at 760 mmHg

[ Melting Point ]:
167-170 °C(lit.)

[ Molecular Formula ]:
C₆H₅Cl₂NO

[ Molecular Weight ]:
178.016

[ Flash Point ]:
137.4±27.9 °C

[ Exact Mass ]:
176.974823

[ PSA ]:
46.25000

[ LogP ]:
1.40

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.661

[ Stability ]:
Stable. Incompatible with acids, acid chlorides, acid anhydrides, chloroformates, strong oxidizing agents.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
SJ5774500

[ Packaging Group ]:
I; II; III

[ Hazard Class ]:
6.1

[ HS Code ]:
2922299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2,6-Dichloro-4-nitrophenol
N,N-Dimethylformamide
2,6-Dichloroquinone-4-chloroimide
2-Amino-4-chlorophenol
2,6-dichloro-4-[(3,5-dichloro-4-hydroxyphenyl)hydrazinylidene]cyclohexa-2,5-dien-1-one
2-chloro-4,4'-azo-di-phenol
2,2'-dichloro-4,4'-azo-di-phenol
2,6,2'-trichloro-4,4'-azo-di-phenol
Phenol,4,4'-(1,2-diazenediyl)bis-

DownStream

2,6-DICHLOROPHENOLINDOPHENOL
2,6-Dichlorophenol
2,6-DICHLORO-1,4-BENZOQUINONE
2,6-Dichloroquinone-4-chloroimide
2,6-Dichloro-4-iodobenzoic acid
Benzenesulfonamide,N-(3,5-dichloro-4-oxo-2,5-cyclohexadien-1-ylidene)-
3,5-dichloro-4-(1,1,2,3,3,3-hexafluoropropoxy)aniline
N-(3,5-dichloro-4-hydroxyphenyl)acetamide
2,6-dichloro-4-[(3,5-dichloro-4-hydroxyphenyl)hydrazinylidene]cyclohexa-2,5-dien-1-one
2,6-dichloro-4-sulfanylphenol

Customs

[ HS Code ]: 2922299090

[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Characterization of methemoglobin formation induced by 3,5-dichloroaniline, 4-amino-2,6-dichlorophenol and 3,5-dichlorophenylhydroxylamine.

Toxicology 118(1) , 23-36, (1997)

3,5-Dichloroaniline is an intermediate in the production of certain fungicides. This study characterized the capacity of 3,5-dichloroaniline and two putative metabolites to induce methemoglobin format...

Fluorescent materials for pH sensing and imaging based on novel 1,4-diketopyrrolo-[3,4-c]pyrrole dyes†Electronic supplementary information (ESI) available: NMR and MS spectra, further sensor characteristics and sensor long-time performance. See DOI: 10.1039/c3tc31130aClick here for additional data file.

J. Mater. Chem. C 1 , 5685-5693, (2013)

New optical pH-sensors relying on 1,4-diketopyrrolo-[3,4-c]pyrroles (DPPs) as fluorescent pH-indicators are presented. Different polymer hydrogels are useful as immobilization matrices, achieving exce...

Theory and practice of enzyme bioaffinity electrodes. Chemical, enzymatic, and electrochemical amplification of in situ product detection.

J. Am. Chem. Soc. 130(23) , 7276-85, (2008)

The two articles in this series are dedicated to bioaffinity electrodes with in situ detection of the product of the enzyme label after recognition by its conjugate immobilized on the electrode. Part ...

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4-AMINO-2,6-DIFLUOROPYRIMIDINE
4-amino-2,6-bis(piperidin-1-ylmethyl)phenol
4-amino-2,6-bis(4-butylphenoxy)-1,5-dihydroxyanthracene-9,10-dione
4-Amino-2,6-dichloropyrimidine-5-carboxaldehyde