Methyl 3-chlorosulfonylthiophene-2-carboxylate

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Names

[ CAS No. ]:
59337-92-7

[ Name ]:
Methyl 3-chlorosulfonylthiophene-2-carboxylate

[Synonym ]:
Methyl-3-(chlorsulfonyl)thiophen-2-carboxylat
2-methoxycarbonyl-3-thiophenesulfonyl chloride
Methylchlorosulfonylthiophenecarboxylate
Methyl 3-(chlorosulfonyl)-2-thiophenecarboxylate
2-(METHOXYCARBONYL)THIOPHENE-3-SULFONYL CHLORIDE
2-(carbomethoxy)thiophene-3-sulfonyl chloride
MFCD00068160
2-Thiophenecarboxylic acid, 3-(chlorosulfonyl)-, methyl ester
2-Carbomethoxy-3-thiophenesulfonyl chloride
Methyl-3-chlorosulfonylthiophene-2-carboxylate
3-(chlorosulfonyl)thiophene-2-carboxylic acid methyl ester
2-(methoxycarbonyl)thiophene-3-sulphonyl chloride
T5SJ BVO1 CSWG

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
364.8±27.0 °C at 760 mmHg

[ Melting Point ]:
61-64 °C(lit.)

[ Molecular Formula ]:
C6H5ClO4S2

[ Molecular Weight ]:
240.684

[ Flash Point ]:
174.4±23.7 °C

[ Exact Mass ]:
239.931778

[ PSA ]:
97.06000

[ LogP ]:
1.57

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.560

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 3

[ WGK Germany ]:
3

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-chlorosulfonyl-thiophene-2-carboxylic acid chloride
  • Methanol
  • Methyl 3-amino-2-thiophenecarboxylate
  • 3-Chlorothiophene-2-carboxylic acid

DownStream

  • Methyl 3-sulfamoyl-2-thiophenecarboxylate
  • methyl 3-[[(E)-(4-nitrophenyl)methylideneamino]sulfamoyl]thiophene-2-carboxylate
  • methyl 3-[(benzylideneamino)sulfamoyl]thiophene-2-carboxylate
  • 3-(N-(4-CHLORO-3-METHYLISOXAZOL-5-YL)SULFAMOYL)THIOPHENE-2-CARBOXYLIC ACID
  • 3-(N-(4-CHLORO-3-METHYLISOXAZOL-5-YL)SULFAMOYL)-N-METHOXY-N-METHYLTHIOPHENE-2-CARBOXAMIDE
  • METHYL 3-(N-(4-CHLORO-3-METHYLISOXAZOL-5-YL)SULFAMOYL)THIOPHENE-2-CARBOXYLATE
  • Methyl 4-hydroxy-2H-thieno[2,3-e][1,2]thiazine-3-carboxylate 1,1-dioxide
  • Tenoxicam
  • METHYL 2-METHYL-4-HYDROXY-2H-THIENO[2,3-E]-1,2-THIAZINE-3-CARBOXYLATE-1,1-DIOXIDE
  • METHYL 3-[(METHOXYCARBONYLMETHYL) SULFAMOYL]THIOPHENE-2-CARBOXYLATE

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis and antiproliferative evaluation of novel benzoimidazole-contained oxazole-bridged analogs of combretastatin A-4.

Eur. J. Med. Chem. 68 , 222-32, (2013)

A series of novel oxazole-bridged analogs of combretastatin A-4 bearing a benzo[d]-imidazole as B ring were synthesized and evaluated for antiproliferative activities against five human cancer cell li...

Gronowitz S.

The Chemistry of Heterocyclic Compounds, The Pyrimidines: Supplement 2 , (2009), 263


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Related Compounds

  • methyl 3-nitropyridine-2-carboxylate
  • methyl 3-isothiocyanatothiophene-2-carboxylate
  • methyl 3-isocyanatopyridine-2-carboxylate
  • methyl 3-acetyloxythiophene-2-carboxylate
  • methyl 3-cyclopropylpyridine-2-carboxylate
  • methyl 3-methoxypyridine-2-carboxylate,hydrochloride
  • 4-bromo-N-[4-({4-[3-(4-fluorophenyl)-1,2,4-oxadiazol-5-yl]-1H-imidazol-1-yl}methyl)phenyl]benzamide
  • N-[4-({4-[3-(3,4-dimethoxyphenyl)-1,2,4-oxadiazol-5-yl]-1H-imidazol-1-yl}methyl)phenyl]-2-fluorobenzamide
  • N-[4-({4-[3-(3,4-dimethoxyphenyl)-1,2,4-oxadiazol-5-yl]-1H-imidazol-1-yl}methyl)phenyl]-3-methoxybenzamide
  • N-[4-({4-[3-(4-fluorophenyl)-1,2,4-oxadiazol-5-yl]-1H-imidazol-1-yl}methyl)phenyl]-4-methoxybenzamide
  • N-[4-({4-[3-(3,4-dimethoxyphenyl)-1,2,4-oxadiazol-5-yl]-1H-imidazol-1-yl}methyl)phenyl]-4-methoxybenzamide
  • 4-ethyl-N-(4-((4-(3-(4-fluorophenyl)-1,2,4-oxadiazol-5-yl)-1H-imidazol-1-yl)methyl)phenyl)benzenesulfonamide
  • 2-methyl-N-[(4-methylphenyl)methyl]-5-(1,2-oxazol-5-yl)furan-3-sulfonamide
  • 4-(tert-butyl)-N-(4-((4-(3-(m-tolyl)-1,2,4-oxadiazol-5-yl)-1H-imidazol-1-yl)methyl)phenyl)benzenesulfonamide
  • 4-chloro-N-(4-((4-(3-(m-tolyl)-1,2,4-oxadiazol-5-yl)-1H-imidazol-1-yl)methyl)phenyl)benzenesulfonamide
  • 2-fluoro-N-(4-((4-(3-(m-tolyl)-1,2,4-oxadiazol-5-yl)-1H-imidazol-1-yl)methyl)phenyl)benzenesulfonamide
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