Methyl 2-methyl-3-nitrobenzoate

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Names

[ CAS No. ]:
59382-59-1

[ Name ]:
Methyl 2-methyl-3-nitrobenzoate

[Synonym ]:
2-Methyl-3-nitro-benzoesaeure-methylester
Methyl 3-nitro-o-toluate
Benzoic acid, 2-methyl-3-nitro-, methyl ester
Methyl 3-nitro-2-methylbenzoate
MFCD00082564
3-Nitro-o-toluic Acid Methyl Ester
2-methyl-3-nitromethylbenzoate
methyl 2-methyl-3-nitro benzoate
Methyl 2-methyl-3-nitrobenzoate
Benzoic acid,2-methyl-3-nitro-,methyl ester
2-methyl-3-nitrobenzoic acid,methyl ester
Methyl2-methyl-3-nitrobenzene carboxylate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
286.6±20.0 °C at 760 mmHg

[ Melting Point ]:
62-65 °C(lit.)

[ Molecular Formula ]:
C9H9NO4

[ Molecular Weight ]:
195.172

[ Flash Point ]:
128.7±23.8 °C

[ Exact Mass ]:
195.053162

[ PSA ]:
72.12000

[ LogP ]:
2.28

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.548

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Precursor & DownStream

Precursor

  • Methanol
  • 2-Methyl-3-nitrobenzoic acid
  • methyl iodide
  • 2-Methyl-3-nitrobenzyl alcohol
  • Methyl o-methylbenzoate
  • N,N-Dimethylformamide dimethyl acetal
  • 2-methyl-3-nitrobenzoyl chloride
  • nitric acid

DownStream

  • 4-Nitroisoindolin-1-one
  • METHYL 4-INDOLECARBOXYLATE
  • 4-amino-2,3-dihydro-1H-isoindol-1-one
  • tert-Butyl 4-(hydroxymethyl)-1H-indole-1-carboxylate
  • 1-TERT-BUTYL 4-METHYL 1H-INDOLE-1,4-DICARBOXYLATE
  • tert-butyl 4-(bromomethyl)-1H-indole-1-carboxylate
  • 4-BROMO-2-NITROBENZYLBROMIDE
  • (3-Amino-2-methylphenyl)methanol
  • 5-Nitro-1(2H)-isoquinolinone
  • Methyl 2-(bromomethyl)-3-nitrobenzoate

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

The Chemistry of Indoles. XII. A Facile Route to 5-Nitroisocoumarins and Methyl Indole-4-carboxylate. Masanori S, et al.

Chem. Pharm. Bull. 29(1) , 249-53, (1981)

Preparation of 2-arylindole-4-carboxylic amide derivatives. Kuethe JT and Davies LW.

Tetrahedron 62(49) , 11381-90, (2006)

Synthesis of 2-Arylindole-4-Carboxylic Amides:[2-(4-Fluorophenyl)-1H-Indol-4-YL]-1-Pyrrolidinylmethanone. Kuethe JT and Beutner GL.

Organic Synth. , 92-104, (2009)


More Articles

Related Compounds

  • Methyl 2-fluoro-5-methyl-3-nitrobenzoate
  • methyl 2-[(4-formylphenoxy)methyl]-3-nitrobenzoate
  • methyl 2-hydroxy-6-methyl-3-nitrobenzoate
  • methyl 2-acetyloxy-4-methyl-3-nitrobenzoate
  • methyl 2-methoxy-6-methyl-3-nitrobenzoate
  • Methyl 2-chloro-6-methyl-3-nitrobenzoate
  • 3-(1-Aminopropyl)-3-hydroxy-8lambda6-thiabicyclo[3.2.1]octane-8,8-dione
  • 3-(1-Amino-2-ethylbutyl)-3-hydroxy-8lambda6-thiabicyclo[3.2.1]octane-8,8-dione
  • 3-(1-Amino-2-methylpropyl)-3-hydroxy-8lambda6-thiabicyclo[3.2.1]octane-8,8-dione
  • 3-Tert-butyl-1-oxo-2,8-dioxaspiro[4.5]decane-3-carboxylic acid
  • 2-{2-[(Tert-butoxy)carbonyl]-2-azaspiro[3.4]octan-1-yl}acetic acid
  • 2-{2-[(Tert-butoxy)carbonyl]-4-methyl-2-azabicyclo[2.1.1]hexan-1-yl}acetic acid
  • 2-{6-[(tert-butoxy)carbonyl]-4H,5H,6H,7H-thieno[2,3-c]pyridin-7-yl}acetic acid
  • 2-{7-[(tert-butoxy)carbonyl]-5H,6H,7H,8H-[1,2,4]triazolo[4,3-a]pyrazin-6-yl}acetic acid
  • 2-{2-[(tert-butoxy)carbonyl]-1H,2H,3H,4H,9H-pyrido[3,4-b]indol-1-yl}acetic acid
  • Ethyl 3-amino-2-methyl-5-sulfamoylbenzoate
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