Trimethylphosphine

Suppliers

Names

[ CAS No. ]:
594-09-2

[ Name ]:
Trimethylphosphine

[Synonym ]:
Phosphine, trimethyl-
Trimethylphosphine
TRIMETHYLPHOSPHORUS
EINECS 209-823-1
MFCD00008510
trimethylphosphane

Chemical & Physical Properties

[ Density]:
0.872 g/mL at 25 °C

[ Boiling Point ]:
40.5±9.0 °C at 760 mmHg

[ Melting Point ]:
−86 °C(lit.)

[ Molecular Formula ]:
C3H9P

[ Molecular Weight ]:
76.077

[ Flash Point ]:
-30.0±0.0 °C

[ Exact Mass ]:
76.044189

[ PSA ]:
13.59000

[ LogP ]:
0.82

[ Vapour Pressure ]:
433.8±0.1 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.428(lit.)

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H315-H319-H335-H351

[ Supplemental HS ]:
May form explosive peroxides.

[ Precautionary Statements ]:
P210-P280-P301 + P312 + P330-P305 + P351 + P338-P370 + P378-P403 + P235

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S9-S16-S26-S36/37/39-S62-S36/37-S7/9-S33

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
I

[ Hazard Class ]:
4.2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • METHYLLITHIUM
  • methylenetriphenylphosphorane-(4,5-diethyl-2,5-dihydro-2,2,3-trimethyl-1-phenyl-1,2,5-phosphasilaborole)
  • tetrakis(trimethylphosphine)platinum(0)
  • Thianaphthene
  • nickel,trimethylphosphanium
  • methyl iodide
  • METHYLMAGNESIUM IODIDE
  • Dimethylzinc
  • Chloromethane

DownStream

  • trimethyl(trimethylsilylmethyl)phosphanium,chloride
  • 1,2,4,5-tetrabromo-3,6-dimethoxybenzene
  • Trimethylphosphine Oxide
  • dimethylphosphoryloxymethane
  • methoxy(dimethyl)phosphane
  • Dimethyl methylphosphonate
  • Trimethylphosphine selenide
  • (PB) trimethylphosphanebis(1,5-cyclooctanediylboryl)monoselenide
  • cis,mer-(trimethylphosphine)3Co(methyl)2I

Articles

Change of surface structure upon foam film formation.

ChemPhysChem 16(4) , 733-8, (2015)

The charge distribution and coverage with surfactant molecules at foam film surfaces plays an important role in determining foam film structure and stability. This work uses the concentration depth pr...

Molybdenum complex with bulky chelates as a functional model for molybdenum oxidases.

Inorg. Chem. 53(23) , 12416-27, (2014)

The novel bulky Schiff base chelate ligand [(4,5-diisopropyl-1H-pyrrole-2-yl)methylene]-4-(tert-butyl)aniline ((iPr2)HL) bearing two isopropyl groups close to the pyrrole nitrogen atom reacts with MoC...

Trimethylphosphine binding to horse-heart and sperm-whale myoglobins. Kinetics, proton magnetic resonance assignment and nuclear Overhauser effect investigation of the heme pocket.

Eur. J. Biochem. 214(2) , 405-14, (1993)

Two-dimensional nuclear magnetic resonance techniques have been used to assign resonances corresponding to the heme pocket and several other residues of horse heart and sperm whale myoglobins ligated ...


More Articles

Related Compounds

  • trimethylphosphine-d9
  • Trimethylphosphine Oxide
  • trimethylphosphine-borane
  • [Ni(trimethylphosphine)4]
  • RhCl(trimethylphosphine)2
  • trimethylphosphine sulfide
  • (S)-2-phenyl-1-(1H-tetrazol-5-yl)ethanamine
  • 5-(4-Methylphenoxy)pyrimidin-2-amine
  • 3-Chloro-1-ethyl-1H-pyrazole-5-carboxylic acid
  • (2E)-3-(1H-indol-4-yl)prop-2-en-1-ol
  • 5-pyrazin-2-yl-1H-indazol-3-amine
  • Tert-butyl 2-prop-1-enylpyrrolidine-1-carboxylate
  • 1-(But-3-enyl)-3-(chloromethyl)benzene
  • methyl 1-[5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrimidin-2-yl]piperidine-3-carboxylate
  • 2-[(3-Methoxyphenyl)sulfanyl]pentan-3-one
  • 2-(Oxazol-2-yl)thiophen-3-amine