Dichloro(triphenyl)stiborane

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Names

[ CAS No. ]:
594-31-0

[ Name ]:
Dichloro(triphenyl)stiborane

[Synonym ]:
Dichloro(triphenyl)stiborane
dichloro(triphenyl)-λ<sup>5</sup>-stibane
MFCD00013598
Antimony, dichlorotriphenyl-
EINECS 209-834-1

Chemical & Physical Properties

[ Melting Point ]:
143-145ºC(lit.)

[ Molecular Formula ]:
C18H15Cl2Sb

[ Molecular Weight ]:
423.978

[ Exact Mass ]:
421.958893

[ LogP ]:
5.83940

[ Storage condition ]:
Refrigerator

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CC5095000
CHEMICAL NAME :
Antimony, dichlorotriphenyl-
CAS REGISTRY NUMBER :
594-31-0
LAST UPDATED :
199712
DATA ITEMS CITED :
28
MOLECULAR FORMULA :
C18-H15-Cl2-Sb
MOLECULAR WEIGHT :
423.98
WISWESSER LINE NOTATION :
G-SB-GR&R&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
195 mg/kg
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1280,1986 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,15,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-FINLAND:.TWA (0.5 mg(Sb)/m3) JAN 1993 OEL-FRANCE:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ANTIMONY-air:10H TWA 0.5 mg(Sb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Hazard Codes ]:
Xn,N

[ Risk Phrases ]:
20/22-51/53

[ Safety Phrases ]:
S61

[ RIDADR ]:
UN 2923 8/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
CC5095000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

Synthetic Route

Precursor & DownStream

Precursor

  • Triphenylstibine
  • Sulfuryl chloride
  • Sulfur dichloride
  • THALLIUM(III) CHLORIDE HYDRATE
  • Disulfur dichloride
  • Chloramine-T
  • Tetraethylammonium chloride
  • 4,5-dichloro-1,2,3-dithiazolylium chloride
  • Hydrochloric acid

DownStream

  • Antimony,chlorotetraphenyl-, (TB-5-12)-
  • 2-Propyn-1-one, 1,3-diphenyl-
  • Acrylophenone
  • Triphenylstibine
  • 2-Phenylthiophene
  • 2-Phenylfuran
  • 4-Methoxybiphenyl
  • Benzoyl thiol
  • Biphenyl
  • 4-Phenyltoluene

Related Compounds

  • dichloro(triphenyl)-λ5-phosphane,germanium
  • dichloro(triphenyl)-λ5-arsane,mercury
  • Dichloro(triphenyl)-λ5-bismuthane
  • dichloro(triphenyl)-λ5-arsane
  • dichloro(triphenyl)stannanuide
  • dichloro(triphenyl)-λ5-phosphane,ruthenium
  • 1-{6,6-Difluoro-3-azabicyclo[3.1.0]hexan-3-yl}-3-fluoropropan-2-ol
  • 3-{4-[(Trifluoromethyl)sulfanyl]phenyl}prop-2-en-1-ol
  • (1S)-1-cyclopropyl-2-(dimethylamino)ethan-1-ol
  • 6-[(2-Methylpent-4-yn-2-yl)amino]pyridine-3-carboxylic acid
  • 4-(1-Isocyanatocyclopropyl)cyclohex-1-ene
  • 4-amino-1-propan-2-yl-5-(1H-pyrrol-2-yl)pyrrolidin-2-one
  • Benzyl 3-cyano-3-cyclopropylpyrrolidine-1-carboxylate
  • rac-2-({[(1R,3S)-3-aminocyclopentyl]methyl}amino)ethan-1-ol
  • N-(4-Chloro-2,3-dimethoxyphenyl)-N-methylacetamide
  • rac-N-[(1R,3S)-3-(aminomethyl)cyclopentyl]cyclopentanecarboxamide
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