methylthiomethyl phenyl sulfone

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Names

[ CAS No. ]:
59431-14-0

[ Name ]:
methylthiomethyl phenyl sulfone

[Synonym ]:
methylthiomethyl phenyl sulphone
Benzolsulfonyl-methylmercapto-methan
[(methylthiomethyl)sulfonyl]benzene
Methylthiomethyl phenyl sulfone
(methylsulfanyl)methyl phenyl sulfone
Methylmercapto-phenylsulfon-methan
benzenesulfonyl-methylsulfanyl-methane
MFCD00075517

Chemical & Physical Properties

[ Density]:
1.251g/cm3

[ Boiling Point ]:
358.4ºC at 760 mmHg

[ Melting Point ]:
85-87ºC(lit.)

[ Molecular Formula ]:
C8H10O2S2

[ Molecular Weight ]:
202.29400

[ Flash Point ]:
170.6ºC

[ Exact Mass ]:
202.01200

[ PSA ]:
67.82000

[ LogP ]:
2.86160

[ Index of Refraction ]:
1.567

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl Methanethiosulfonate
  • 2-(phenylsulfonyl)acetophenone
  • 1-chloro-4-methylsulfanylsulfonylbenzene
  • CHLOROMETHYL PHENYL SULFONE
  • Sodium thiomethoxide
  • Methylthiomethyl Acetate
  • Sodium benzenesulfinate
  • Dimethyl disulfide
  • (Phenylsulfonyl)acetic acid

DownStream

  • (Z)-1,2-bis(methylsulfanyl)ethene
  • (E)-1,2-bis(methylsulfanyl)ethene
  • 1-(benzenesulfonyl)but-3-en-2-yl-trimethylsilane
  • [1-(benzenesulfonyl)-3-methylbut-3-en-2-yl]-trimethylsilane
  • [2-(benzenesulfonyl)-2-methylsulfanylethyl]-trimethylsilane
  • 2-(benzenesulfonyl)ethenyl-trimethylsilane

Articles

An asymmetric approach to 2-deoxynucleosides via organosulfur building blocks as chemical chameleons.

Carbohydr. Res. 202 , 1-12, (1990)

An asymmetric synthesis of 6-N-benzoyl-5'-O-benzyl-2'-deoxyadenosine and its a anomer from non-carbohydrate building blocks is achieved in 7 steps. The sequence builds the basic structures using bis(m...

Rigid, conjugated and shaped arylethynes as mediators for the assembly of gold nanoparticles. Yan H, et al.

J. Mater. Chem. 21(6) , 1890-1901, (2011)

Efficient One-Pot Preparation of Methylthio Arylbutadiynes by Double Elimination Protocol. Su Q, et al.

Synth. Commun. 43(19) , 2648-55, (2019)


More Articles

Related Compounds

  • Methyl phenyl sulfone
  • Allyl phenyl sulfone
  • diiodovinyl phenyl sulfone
  • Fluoromethyl phenyl sulfone
  • Difluoroiodomethyl phenyl sulfone
  • BroModifluoroMethyl phenyl sulfone
  • N-([2,3'-bipyridin]-5-ylmethyl)-4-fluoro-2-methylbenzenesulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)-2-ethoxybenzenesulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)-3-fluoro-4-methoxybenzenesulfonamide
  • N-([2,3'-bipyridin]-5-ylmethyl)-3-chloro-2-methylbenzenesulfonamide
  • N-((1r,4r)-4-(pyridin-2-yloxy)cyclohexyl)isoxazole-5-carboxamide
  • 2-methyl-N-((1r,4r)-4-(pyridin-2-yloxy)cyclohexyl)thiazole-4-carboxamide
  • 1-methyl-6-oxo-N-((1r,4r)-4-(pyridin-2-yloxy)cyclohexyl)-1,6-dihydropyridazine-3-carboxamide
  • 3-(3,5-dimethylisoxazol-4-yl)-N-((1r,4r)-4-(pyridin-2-yloxy)cyclohexyl)propanamide
  • 3-(4-oxoquinazolin-3(4H)-yl)-N-((1r,4r)-4-(pyridin-2-yloxy)cyclohexyl)propanamide
  • 2-(4-oxoquinazolin-3(4H)-yl)-N-((1r,4r)-4-(pyridin-2-yloxy)cyclohexyl)acetamide
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