1,3-diacetoxy-1,1,3,3-tetrabutyldistannoxane

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Names

[ CAS No. ]:
5967-09-9

[ Name ]:
1,3-diacetoxy-1,1,3,3-tetrabutyldistannoxane

[Synonym ]:
Acetoxydibutyltinoxide
1,1,3,3-tetra-n-butyl-1,3-diacetoxy distannoxane
oxybis(acetoxydibutyl-ti
diacetatotetrabutyldistannoxane
Oxybis[acetoxydibutylstannane]
BIS(DIBUTYLACETOXYTIN)OXIDE
Tetrabutyldiaceloxydistannoxane
tetrabutyldistannoxane
1,3-diacetoxy 1,1,3,3-tetrabutyl distannoxane
DIACETOXYTETRABUTYLIN OXIDE
bis(acetoxydibutylstannane)oxide
1,3-bis(acetyloxy)tetrabutyldistannoxane
MFCD00008696
EINECS 227-755-0
diacetoxytetrabutyldistannoxane

Chemical & Physical Properties

[ Boiling Point ]:
459.48ºC at 760 mmHg

[ Melting Point ]:
56-58ºC(lit.)

[ Molecular Formula ]:
C20H42O5Sn2

[ Molecular Weight ]:
599.94600

[ Flash Point ]:
>150ºC

[ Exact Mass ]:
602.10800

[ PSA ]:
61.83000

[ LogP ]:
6.21400

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
JN8740000
CHEMICAL NAME :
Distannoxane, 1,3-diacetoxy-1,1,3,3-tetrabutyl-
CAS REGISTRY NUMBER :
5967-09-9
LAST UPDATED :
199712
DATA ITEMS CITED :
25
MOLECULAR FORMULA :
C20-H42-O5-Sn2
MOLECULAR WEIGHT :
600.00
WISWESSER LINE NOTATION :
1VO-SN-4&4&O-SN-4&4&OV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
320 mg/kg
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02081 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Sn)/m3;STEL 0.2 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,258,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Sn)/m3;STEL 0.3 mg(Sn)/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-HUNGARY:STEL 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-SWEDEN:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-THAILAND:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ORGANOTIN COMPOUND-air:10H TWA 0.1 mg(Sn)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312 + H332-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
20/21/22-34

[ Safety Phrases ]:
S26;S27;S28;S45;S36/S37/S39

[ RIDADR ]:
UN 1759 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
JN8740000

[ Packaging Group ]:
III

Synthetic Route

Precursor & DownStream

Precursor

  • tri-n-butyltin acetate

DownStream

  • butyl acetate
  • DIBUTYLBUTOXYTIN
  • butoxy-[butoxy(dibutyl)stannyl]oxy-dibutylstannane
  • [dibutyl-[dibutyl(methoxy)stannyl]oxystannyl] acetate

Related Compounds

  • 1,3-diacetoxy-1,1,3,3-tetrabutyldistannoxane
  • 1,3-diacetoxy-1,1,3,3-tetraoctyldistannoxane
  • 1,3-diacetoxy-1,1,3,3-tetramethyldistannoxane
  • 1H-Azepine,1-[bis(1-aziridinyl)phosphinothioyl]hexahydro-
  • 1,3-dimethoxy-1,1,3,3-tetrabutyldistannoxane
  • 1,3-diazido-1,1,3,3-tetrabutyldistannoxane
  • 1-(3-Methoxyphenyl)-1H-pyrazol-4-OL
  • 6-Hydroxy-1-benzothiophene-3-carbaldehyde
  • O-[2-(pyridin-4-yl)propan-2-yl]hydroxylamine
  • 3-(Thiolan-2-yl)but-3-en-1-amine
  • 5,5-Dimethyl-3-methylidenehexan-1-amine
  • 2-(4-Aminobut-1-en-2-yl)phenol
  • 2-(6-chloro-1-methyl-1H-indol-3-yl)propan-2-ol
  • 3-Cyclobutylbut-3-en-1-amine
  • 3-Propylimidazo[1,5-a]pyridin-7-amine
  • 1-Piperidin-4-ylmethyl-1H-pyrazol-4-ol
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