sec-Butyllithium solution

Names

[ CAS No. ]:
598-30-1

[ Name ]:
sec-Butyllithium solution

[Synonym ]:
lithium,butane
EINECS 209-927-7
MFCD00009323

Chemical & Physical Properties

[ Density]:
0.769 g/mL at 25 °C

[ Molecular Formula ]:
C₄H₉Li

[ Molecular Weight ]:
64.05530

[ Flash Point ]:
1 °F

[ Exact Mass ]:
64.08640

[ LogP ]:
1.75410

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H250-H260-H304-H314-H336-H410

[ Precautionary Statements ]:
P210-P222-P223-P231 + P232-P370 + P378-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R15;R17;R34;R51/53;R65;R66;R67

[ Safety Phrases ]:
S26-S36/37/39-S43-S45-S60-S61-S62

[ RIDADR ]:
UN 3394 4.2/PG 1

[ WGK Germany ]:
2

[ Packaging Group ]:
I

[ Hazard Class ]:
4.3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Chlorobutane
sec-Butyl magnesium chloride
Lithium

DownStream

Morpholine-4-carbaldehyde
Morpholine, 4,4'-carbonylbis
1,2-dimorpholin-4-ylethane-1,2-dione
3-Methyl-2-pentanone
3,4-Dimethylhexane
2-[(tert-butyldimethylsilyl)oxy]-4,6-dimethyl-4-sec-butyl-4H-pyran
4-Methyl-1-hexene
2,3-Diphenyl-2,3-butanediol

Articles

Thin films of homopolymers and cylinder-forming diblock copolymers under shear.

ACS Nano 8(8) , 8015-26, (2014)

We study thin films of homopolymers (PS) and monolayers of cylinder-forming diblock copolymers (PS–PHMA) under shear. To this end, we employed both experiments and computer simulations that correctly ...

Chelation-assisted substrate-controlled asymmetric lithiation-allylboration of chiral carbamate 1,2,4-butanetriol acetonide.

Molecules 20 , 9890-905, (2015)

The lithiation of 2-(2,2-dimethyl-1,3-dioxolan-4-yl)ethyl diisopropylcarbamate (1) is achieved freely by sec-butyllithium in diethylether with high lk-diastereoselectivity: the bicyclic chelate comple...

Membranes with artificial free-volume for biofuel production.

Nat. Commun. 6 , 7529, (2015)

Free-volume of polymers governs transport of penetrants through polymeric films. Control over free-volume is thus important for the development of better membranes for a wide variety of applications s...

3-[1-({[(4-methoxyphenyl)carbamoyl]methyl}sulfanyl)-5-oxo-4H,5H-[1,2,4]triazolo[4,3-a]quinazolin-4-yl]-N-(propan-2-yl)propanamide
4-(4-methylpiperazin-1-yl)-2-nitro-N-(5-phenylmethoxy-1H-indazol-3-yl)benzamide
N-[5-[(3,5-difluorophenyl)methoxy]-1H-indazol-3-yl]-4-(4-methylpiperazin-1-yl)-2-nitrobenzamide
N-[5-[(3,5-difluorophenyl)methoxy]-1H-indazol-3-yl]-2-fluoro-4-(4-methylpiperazin-1-yl)benzamide
N-[5-[(3,5-difluorophenyl)methoxy]-1H-indazol-3-yl]-2-[(1-methoxy-2-methylpropan-2-yl)amino]-4-(4-methylpiperazin-1-yl)benzamide
ethyl 4-[2-[[5-[(3,5-difluorophenyl)methoxy]-1H-indazol-3-yl]carbamoyl]-5-(4-methylpiperazin-1-yl)anilino]piperidine-1-carboxylate
2-(benzylamino)-N-[5-[(3,5-difluorophenyl)methoxy]-1H-indazol-3-yl]-4-(4-methylpiperazin-1-yl)benzamide
N-[5-[(3,5-difluorophenyl)methoxy]-1H-indazol-3-yl]-2-(2-fluoroethylamino)-4-(4-methylpiperazin-1-yl)benzamide
3-[1-({[(3-methylbutyl)carbamoyl]methyl}sulfanyl)-5-oxo-4H,5H-[1,2,4]triazolo[4,3-a]quinazolin-4-yl]-N-(propan-2-yl)propanamide
N-(3,5-dichlorophenyl)-2-[(2-methyl-6-pyridin-2-ylpyrimidin-4-yl)thio]acetamide

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