sec-Butyllithium solution

Suppliers

Names

[ CAS No. ]:
598-30-1

[ Name ]:
sec-Butyllithium solution

[Synonym ]:
lithium,butane
EINECS 209-927-7
MFCD00009323

Chemical & Physical Properties

[ Density]:
0.769 g/mL at 25 °C

[ Molecular Formula ]:
C4H9Li

[ Molecular Weight ]:
64.05530

[ Flash Point ]:
1 °F

[ Exact Mass ]:
64.08640

[ LogP ]:
1.75410

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H250-H260-H304-H314-H336-H410

[ Precautionary Statements ]:
P210-P222-P223-P231 + P232-P370 + P378-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R15;R17;R34;R51/53;R65;R66;R67

[ Safety Phrases ]:
S26-S36/37/39-S43-S45-S60-S61-S62

[ RIDADR ]:
UN 3394 4.2/PG 1

[ WGK Germany ]:
2

[ Packaging Group ]:
I

[ Hazard Class ]:
4.3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Chlorobutane
  • sec-Butyl magnesium chloride
  • Lithium

DownStream

  • Morpholine-4-carbaldehyde
  • Morpholine, 4,4'-carbonylbis
  • 1,2-dimorpholin-4-ylethane-1,2-dione
  • 3-Methyl-2-pentanone
  • 3,4-Dimethylhexane
  • 2-[(tert-butyldimethylsilyl)oxy]-4,6-dimethyl-4-sec-butyl-4H-pyran
  • 4-Methyl-1-hexene
  • 2,3-Diphenyl-2,3-butanediol

Articles

Thin films of homopolymers and cylinder-forming diblock copolymers under shear.

ACS Nano 8(8) , 8015-26, (2014)

We study thin films of homopolymers (PS) and monolayers of cylinder-forming diblock copolymers (PS–PHMA) under shear. To this end, we employed both experiments and computer simulations that correctly ...

Chelation-assisted substrate-controlled asymmetric lithiation-allylboration of chiral carbamate 1,2,4-butanetriol acetonide.

Molecules 20 , 9890-905, (2015)

The lithiation of 2-(2,2-dimethyl-1,3-dioxolan-4-yl)ethyl diisopropylcarbamate (1) is achieved freely by sec-butyllithium in diethylether with high lk-diastereoselectivity: the bicyclic chelate comple...

Membranes with artificial free-volume for biofuel production.

Nat. Commun. 6 , 7529, (2015)

Free-volume of polymers governs transport of penetrants through polymeric films. Control over free-volume is thus important for the development of better membranes for a wide variety of applications s...


More Articles

Related Compounds

  • 2-Chloro-1-(6-phenylmethoxy-2-azaspiro[3.3]heptan-2-yl)propan-1-one
  • rac-1-[(4aR,7aS)-4a-(hydroxymethyl)-octahydro-1H-cyclopenta[b]pyridin-1-yl]-2-chloroethan-1-one
  • 2-Chloro-N-(4,5,6,7-tetrahydropyrazolo[1,5-a]pyridin-5-yl)propanamide
  • 4-Methyl-2-(oxiran-2-yl)pyridine
  • N-[5-(2-Methylphenyl)-1,3-thiazol-2-yl]-1-prop-2-enoylpiperidine-4-carboxamide
  • Tert-butyl 2-[(2-chloroacetamido)methyl]-5,5-dimethylmorpholine-4-carboxylate
  • Tert-butyl 5,5-dimethyl-2-[(prop-2-enamido)methyl]morpholine-4-carboxylate
  • N-(3-(Methylsulfonamidomethyl)benzyl)acrylamide
  • N-(2-Methyl-3-oxo-1H-isoindol-4-yl)prop-2-enamide
  • 2-Chloro-N-(6-thiomorpholin-4-ylpyridin-2-yl)acetamide
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