sec-Butyllithium solution

Suppliers

Names

[ CAS No. ]:
598-30-1

[ Name ]:
sec-Butyllithium solution

[Synonym ]:
lithium,butane
EINECS 209-927-7
MFCD00009323

Chemical & Physical Properties

[ Density]:
0.769 g/mL at 25 °C

[ Molecular Formula ]:
C4H9Li

[ Molecular Weight ]:
64.05530

[ Flash Point ]:
1 °F

[ Exact Mass ]:
64.08640

[ LogP ]:
1.75410

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H250-H260-H304-H314-H336-H410

[ Precautionary Statements ]:
P210-P222-P223-P231 + P232-P370 + P378-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R15;R17;R34;R51/53;R65;R66;R67

[ Safety Phrases ]:
S26-S36/37/39-S43-S45-S60-S61-S62

[ RIDADR ]:
UN 3394 4.2/PG 1

[ WGK Germany ]:
2

[ Packaging Group ]:
I

[ Hazard Class ]:
4.3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Chlorobutane
  • sec-Butyl magnesium chloride
  • Lithium

DownStream

  • Morpholine-4-carbaldehyde
  • Morpholine, 4,4'-carbonylbis
  • 1,2-dimorpholin-4-ylethane-1,2-dione
  • 3-Methyl-2-pentanone
  • 3,4-Dimethylhexane
  • 2-[(tert-butyldimethylsilyl)oxy]-4,6-dimethyl-4-sec-butyl-4H-pyran
  • 4-Methyl-1-hexene
  • 2,3-Diphenyl-2,3-butanediol

Articles

Thin films of homopolymers and cylinder-forming diblock copolymers under shear.

ACS Nano 8(8) , 8015-26, (2014)

We study thin films of homopolymers (PS) and monolayers of cylinder-forming diblock copolymers (PS–PHMA) under shear. To this end, we employed both experiments and computer simulations that correctly ...

Chelation-assisted substrate-controlled asymmetric lithiation-allylboration of chiral carbamate 1,2,4-butanetriol acetonide.

Molecules 20 , 9890-905, (2015)

The lithiation of 2-(2,2-dimethyl-1,3-dioxolan-4-yl)ethyl diisopropylcarbamate (1) is achieved freely by sec-butyllithium in diethylether with high lk-diastereoselectivity: the bicyclic chelate comple...

Membranes with artificial free-volume for biofuel production.

Nat. Commun. 6 , 7529, (2015)

Free-volume of polymers governs transport of penetrants through polymeric films. Control over free-volume is thus important for the development of better membranes for a wide variety of applications s...


More Articles

Related Compounds

  • N-(3-chloro-2-methylphenyl)-4-(3-(3-methoxyphenyl)-6-oxopyridazin-1(6H)-yl)butanamide
  • N-(2-chlorobenzyl)-4-(3-(3-methoxyphenyl)-6-oxopyridazin-1(6H)-yl)butanamide
  • N-(2,4-dichlorophenyl)-4-(3-(3-methoxyphenyl)-6-oxopyridazin-1(6H)-yl)butanamide
  • Benzo[a]phenoxazin-7-ium, 5-amino-9-(diethylamino)-, sulfate (1:1)
  • 4-(3-(3-methoxyphenyl)-6-oxopyridazin-1(6H)-yl)-N-(2-(methylthio)phenyl)butanamide
  • 3-(3,4-Dimethylphenyl)piperidine
  • 3-Nitro-4-[(2-pyrimidinylthio)methyl]benzoic acid
  • N-cyclopentyl-4-(3-(3,4-dimethoxyphenyl)-6-oxopyridazin-1(6H)-yl)butanamide
  • N-benzyl-4-(3-(3,4-dimethoxyphenyl)-6-oxopyridazin-1(6H)-yl)butanamide
  • 4-(3-(3,4-dimethoxyphenyl)-6-oxopyridazin-1(6H)-yl)-N-(thiophen-2-ylmethyl)butanamide
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