2-Chloropropanoic acid

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Names

[ CAS No. ]:
598-78-7

[ Name ]:
2-Chloropropanoic acid

[Synonym ]:
QVYG1
2-Chloropropionicacid
2-Chloropropanoic acid
2-chloro-propionicaci
EINECS 209-952-3
2-Chloropropionic ac
Propionic acid, α-chloro-
RARECHEM AL BO 1240
2-chloropropionic
2-chloro-propanoicaci
Propanoic acid, 2-chloro-
MFCD00004224
α-Monochloropropanoic acid
2-Chlorpropionsure

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
189.0±13.0 °C at 760 mmHg

[ Melting Point ]:
-12--14 °C

[ Molecular Formula ]:
C3H5ClO2

[ Molecular Weight ]:
108.524

[ Flash Point ]:
101.7±0.0 °C

[ Exact Mass ]:
107.997810

[ PSA ]:
37.30000

[ LogP ]:
0.30

[ Vapour Pressure ]:
0.3±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.441

[ Stability ]:
Stable. Incompatible with strong oxidizing agents, strong bases.

[ Water Solubility ]:
freely soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UE8575000
CHEMICAL NAME :
Propionic acid, 2-chloro-
CAS REGISTRY NUMBER :
598-78-7
BEILSTEIN REFERENCE NO. :
1720259
LAST UPDATED :
199712
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C3-H5-Cl-O2
MOLECULAR WEIGHT :
108.53
WISWESSER LINE NOTATION :
QVYG1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Kidney, Ureter, Bladder - hematuria Skin and Appendages - hair
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555355
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Kidney, Ureter, Bladder - hematuria Skin and Appendages - hair
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555355
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
126 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 5,136(89),1986 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7182 mg/kg/42D-C
TOXIC EFFECTS :
Gastrointestinal - changes in structure or function of esophagus Skin and Appendages - hair Related to Chronic Data - changes in testicular weight
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555355 *** REVIEWS *** ACGIH TLV-TWA 0.44 mg/m3 (0.1 ppm) (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 2 mg/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R21/22;R35

[ Safety Phrases ]:
S23-S26-S28-S36-S45-S36/37/39-S28A

[ RIDADR ]:
UN 2511 8/PG 3

[ WGK Germany ]:
1

[ RTECS ]:
UE8575000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29159080

Synthetic Route

Precursor & DownStream

Precursor

  • DL-Alanine
  • Propanoyl chloride
  • 2-Chloropropionitrile
  • 2-Propanol, 1-nitro-
  • (E)-1-nitroprop-1-ene
  • 2-hydroxypropionic acid
  • 1,3-dichlorobutan-2-one
  • 3-Chloro-2-butanone

DownStream

  • 2-(2-naphthyloxy)propanoic acid
  • 2,3-Dichloropropionic acid
  • Diclofop
  • 2-Phenoxypropanoic acid
  • UNII:FDN17EXK1J
  • 1H-Benzimidazole,2-(1-chloroethyl)-(9CI)
  • butan-2-yl 2-chloropropanoate
  • Benzoic acid,2-[(1-carboxyethyl)amino]-
  • D-alanine
  • L-alanine

Customs

[ HS Code ]: 29159080

Articles

Haloalkanoate dehalogenase II (DehE) of a Rhizobium sp.--molecular analysis of the gene and formation of carbon monoxide from trihaloacetate by the enzyme.

Eur. J. Biochem. 250(3) , 789-93, (1997)

A 3-kb EcoRI fragment of genomic DNA from a Rhizobium sp. cloned into pUC19 endowed Escherichia coli K-12 with the ability to grow, albeit slowly, with 2-chloropropionic acid as substrate. The constru...

Direct determination of the enantiomeric purity or enantiomeric composition of methylpropionates using a single capacitive microsensor.

Anal. Chem. 81(5) , 1969-75, (2009)

Capacitive enantioselective sensors have been demonstrated to provide antipodal signals upon dosage of, e.g., the enantiomers of methyl lactate or methyl-2-chloropropionate. In a next step, these sens...

Use of structure-activity relationships for probing biochemical mechanisms: glutathione transferase zeta conjugation of haloacids.

Adv. Exp. Med. Biol. 500 , 23-31, (2001)


More Articles


Related Compounds

  • 2-CHLOROPROPANOIC ACID
  • D-2-Chloropropanoic acid
  • (±)-2-Chloropropanoic acid
  • (r)-(+)-2-chloropropanoic acid
  • 2-Chloropropanoic acid,morpholide
  • 2-Chloropropanoic acid butyl ester
  • (2S,4R)-1-[(2S)-2-(butanoylamino)-3,3-dimethyl-butanoyl]-4-hydroxy-N-[[4-(4-methylthiazol-5-yl)phenyl]methyl]pyrrolidine-2-carboxamide
  • 10-[2-[2-(2,6-Dioxo-3-piperidyl)-1,3-dioxo-isoindolin-4-yl]oxyethylamino]-10-oxo-decanoic acid
  • Lenalidomide-5'-CO-PEG4-propargyl
  • (2S,4R)-1-[(2S)-2-[[(2S)-2-aminopropanoyl]amino]-3,3-dimethyl-butanoyl]-4-hydroxy-N-[[4-(4-methylthiazol-5-yl)phenyl]methyl]pyrrolidine-2-carboxamide
  • Phthalimidinoglutarimide-5'-propargyl-O-PEG3-C2-acid
  • (2S,4R)-4-hydroxy-1-[(2S)-2-(3-hydroxypropanoylamino)-3,3-dimethyl-butanoyl]-N-[[4-(4-methylthiazol-5-yl)phenyl]methyl]pyrrolidine-2-carboxamide
  • 8-[3-[2-(2,6-Dioxo-3-piperidyl)-1-oxo-isoindolin-4-yl]prop-2-ynoxy]octyl methanesulfonate
  • 11-bromo-N-[2-(2,6-dioxo-3-piperidyl)-1-oxo-isoindolin-4-yl]undecanamide
  • 2-[[2-(2,6-dioxo-3-piperidyl)-1,3-dioxo-isoindolin-4-yl]amino]-N-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethyl]acetamide
  • Phthalimidinoglutarimide-5'-C3-O-PEG3-C2-acid
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