l-3-hydroxy-n-methylmorphinan dihydrate

Names

[ CAS No. ]:
5985-38-6

[ Name ]:
l-3-hydroxy-n-methylmorphinan dihydrate

[Synonym ]:
LEVORPHANOL TARTRATE SALT
LEVORPHANOL TARTRATE
levorphanol tartrate dihydrate
LEVORPHANOLTARTRATE,USP
levorphanol tartrate methanol solution
L-3-HYDROXY-N-METHYLMORPHINAN

Chemical & Physical Properties

[ Boiling Point ]:
410.4ºC at 760 mmHg

[ Molecular Formula ]:
C21H33NO9

[ Molecular Weight ]:
443.48800

[ Flash Point ]:
11ºC

[ Exact Mass ]:
443.21600

[ PSA ]:
156.99000

[ LogP ]:
0.76710

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QD1924200
CAS REGISTRY NUMBER :
5985-38-6
LAST UPDATED :
199012
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C17-H23-N-O.C4-H6-O6.2H2-O
MOLECULAR WEIGHT :
443.55
WISWESSER LINE NOTATION :
T6 G665/FP 2AF P FX ONT&TTJ IQ O1 &QVYQYQVQ &QH 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
135 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - altered sleep time (including change in righting reflex) Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 85,387,1951
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
45 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 85,387,1951
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
23 mg/kg
TOXIC EFFECTS :
Behavioral - altered sleep time (including change in righting reflex) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 85,387,1951

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312 + H332-H317-H334-H360

[ Precautionary Statements ]:
Missing Phrase - N15.00950417-P201-P261-P280-P284-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T,F

[ Risk Phrases ]:
R61

[ Safety Phrases ]:
53-22-36/37-45-16-7

[ RIDADR ]:
UN 1544 6.1/PG 3

[ RTECS ]:
QD1924200

Synthetic Route

Precursor & DownStream

Precursor

  • l-DROMORAN TARTRATE

DownStream

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J. Pharmacol. Exp. Ther. 289 , 965, (1999)

Effects of low (butorphanol, nalbuphine)-, intermediate (buprenorphine)-, and high (morphine, levorphanol)-efficacy mu opioids were examined in F344, Sprague-Dawley (SD), Long-Evans (LE), and Lewis ra...

Characterization and distribution of a cloned rat mu-opioid receptor.

J. Neurochem. 64 , 14-24, (1995)

We have cloned and expressed a rat brain cDNA, TS11, that encodes a mu-opioid receptor based on pharmacological, physiological, and anatomical criteria. Membranes were prepared from COS-7 cells transi...


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Related Compounds

  • Lexacalcitol
  • l-DROMORAN TARTRATE
  • DEXTRORPHAN D-TARTRATE
  • (-)-2-Allyl-3-hydroxy-N-methylmorphinan citrate
  • Dextrorphan-d3 tartrate (d-3-hydroxy-N-Methylmorphinan tartrate-d3)
  • levorphanol
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • Tert-butyl n-[2-(prop-2-ynoyl)phenyl]carbamate
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 2-(4-Methoxy-3-methylsulfanyl-phenyl)-5,5-dimethyl-[1,3]dioxane
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 2-amino-4-fluoro-N,N-dimethylbenzamide