(S)-(-)-Limonene

Suppliers

Names

[ Name ]:
(S)-(-)-Limonene

[Synonym ]:
(4S)-1-methyl-4-prop-1-en-2-ylcyclohexene
(-)-Limonene
(-)-p-Mentha-1,8-diene
S-(-)-LIMONENE
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (S)-
EINECS 227-815-6
MFCD00001558
(4S)-4-Isopropenyl-1-methylcyclohexene
(-)-(4S)-Limonene
(4S)-1-Methyl-4-(prop-1-en-2-yl)cyclohexene
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4S)-
4-Isopropenyl-1-methyl-1-cyclohexene
UNII-47MAJ1Y2NE
p-Mentha-1,8-diene, (S)-(-)-
(S)-Limonene
L-Limonen
Limonene
(-)-(S)-limonene
L-limonene

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
175.4±20.0 °C at 760 mmHg

[ Melting Point ]:
-104--84ºC

[ Molecular Formula ]:
C₁₀H₁₆

[ Molecular Weight ]:
136.234

[ Flash Point ]:
42.8±0.0 °C

[ Exact Mass ]:
136.125198

[ LogP ]:
4.45

[ Vapour Pressure ]:
1.5±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.468

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: OS8350000

CHEMICAL NAME :: p-Mentha-1,8-diene, (S)-(-)-

CAS REGISTRY NUMBER :: 5989-54-8

LAST UPDATED :: 199712

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C10-H16

MOLECULAR WEIGHT :: 136.26

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,809,1978 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9663 No. of Facilities: 36 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 1843 (estimated) No. of Female Employees: 286 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H317-H410

[ Precautionary Statements ]:
P273-P280-P501

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R10;R38;R43;R50/53

[ Safety Phrases ]:
S24-S37-S60-S61

[ RIDADR ]:
UN 2052

[ WGK Germany ]:
2

[ RTECS ]:
OS8350000

[ Packaging Group ]:
III

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(R)-(+)-binaphthol mononeryl ether
(Z)-1-bromo-3,7-dimethyl-octa-2,6-diene
cis-3,7-Dimethyl-2,6-octadien-1-ol
(+)-alpha-Pinene
Beta-pinene
(1S)-(-)-Alpha-Pinene
isoprene
(R,E)-(2,2-dimethyl-1-((2-methylbuta-1,3-dien-1-yl)oxy)propyl)benzene
(S,E)-(2-methyl-1-((2-methylbuta-1,3-dien-1-yl)oxy)propyl)benzene

DownStream

DL-carvone
2-p-Tolyl-1-propene
(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enol
(-)-Perillaldehyde
(E)-carveol
2-Cyclohexen-1-ol,2-methyl-5-(1-methylethenyl)-, (1R,5R)-rel-
cis-(S)-(-)-limonene oxide
cis-(S)-4-Isopropenyl-1-methylcyclohexene 1,2-epoxide
(-)-Carveol

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