ethyl 2,2,2-tribromoacetate

Names

[ CAS No. ]:
599-99-5

[ Name ]:
ethyl 2,2,2-tribromoacetate

[Synonym ]:
tribromo-acetic acid ethyl ester
ethyl ester of tribromoacetic acid
Tribrom-essigsaeure-aethylester
Tribromessigsaeure-ethylester
Ethyl tribromoacetate

Chemical & Physical Properties

[ Density]:
2.359g/cm3

[ Boiling Point ]:
290.8ºC at 760 mmHg

[ Molecular Formula ]:
C4H5Br3O2

[ Molecular Weight ]:
324.79300

[ Flash Point ]:
129.7ºC

[ Exact Mass ]:
321.78400

[ PSA ]:
26.30000

[ LogP ]:
2.38800

[ Index of Refraction ]:
1.575

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AJ7600000
CHEMICAL NAME :
Acetic acid, 2,2,2-tribromoethyl ester
CAS REGISTRY NUMBER :
599-99-5
BEILSTEIN REFERENCE NO. :
1762051
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C4-H5-Br3-O2
MOLECULAR WEIGHT :
324.82
WISWESSER LINE NOTATION :
EXEE1OV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1500 mg/kg
TOXIC EFFECTS :
Behavioral - sleep
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 63,183,1938

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H318

[ Precautionary Statements ]:
P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ RIDADR ]:
UN 2810 6.1 / PGIII

[ RTECS ]:
AJ7600000

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-bromo-1,1-diethoxyethene
  • Propanedioic acid,2,2-dibromo-, 1,3-diethyl ester
  • Ethanol
  • 1,1,1,3,3,3-Hexabromoacetone
  • Tribromacetic acid
  • Ethene,1,1,2,2-tetrabromo-
  • Tribromoacetaldehyde
  • ch3cho
  • TRIETHOXYALUMINUM
  • tribromoacetic acid bromide

DownStream

  • Ethyl dibromo(fluoro)acetate
  • 2,2,2-Tribromoacetamide

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • 1-(2-methylpropoxy)ethyl 2,2,2-tribromoacetate
  • ethyl 2-[2-(2-nitrophenyl)ethenyl]benzoate
  • ethyl 2-[2-(2-nitrophenyl)ethyl]-3-oxo-butanoate
  • ethyl 2-[[(2,2-dimethyl-3H-1-benzofuran-7-yl)oxycarbonyl-methylamino]sulfanyl-octylamino]acetate
  • ethyl 2-[2-[(2-methylpropan-2-yl)oxycarbonylamino]-1,3-thiazol-4-yl]acetate
  • ethyl 2-[2,2-bis(phenylsulfanyl)propyl]pent-4-enoate