BINOL

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Names

[ CAS No. ]:
602-09-5

[ Name ]:
BINOL

[Synonym ]:
BINOL
1,1'-Binaphthalene-2,2'-diol
EINECS 210-014-0
(R)-(+)-1,1'-Bi-2-naphthol
1,1′-binaphthyl-2,2′-diol
(S)-1,1-Bi-2-Naphthol
β-Binaphthol
2,2'-Dihydroxy-1,1'-binaphthalene
(R,S)-Binol
1,1'-Bi-2,2'-naphthols
1,1'-Binaphthalen-2,2'-diol
(S)-(-)-1,1'-Bi-2-naphthol
b-Binaphthol
(1,1-BINAPHTHALENE)-2,2'-DIOL, (±)-
(R)-1,1'-Bi-2-naphthol
(±)-BINOL
1,1'-bi(2-naphthol)
[1,1'-Binaphthalene]-2,2'-diol
MFCD00004068

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
462.1±30.0 °C at 760 mmHg

[ Melting Point ]:
215-218ºC

[ Molecular Formula ]:
C20H14O2

[ Molecular Weight ]:
286.324

[ Flash Point ]:
218.9±19.2 °C

[ Exact Mass ]:
286.099365

[ PSA ]:
40.46000

[ LogP ]:
4.36

[ Vapour Pressure ]:
0.0±1.2 mmHg at 25°C

[ Index of Refraction ]:
1.758

[ Water Solubility ]:
dioxane: 50 mg/mL, clear | insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DU3106000
CHEMICAL NAME :
(1,1'-Binaphthalene)-2,2'-diol
CAS REGISTRY NUMBER :
602-09-5
BEILSTEIN REFERENCE NO. :
0997518
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C20-H14-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
42 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 14,111,1985

Safety Information

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R25;R36/37/38

[ Safety Phrases ]:
S26-S37/39-S45

[ RIDADR ]:
UN 2811

[ WGK Germany ]:
3

[ RTECS ]:
DU3106100

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29072900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromo-2-naphthol
  • 2-Naphthol
  • 2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • [1,1'-Binaphthalene]-2,2'-diol dibutanoate
  • 7,22-dihydro-8,21-dioxa-tetranaphtho[2,1-b:1',2'-d:2'',1''-h:1''',2'''-j]cyclododecene
  • 1-Iodo-2-naphthol
  • (R)-2,2'-methylenedioxy-1,1'-binaphthalene
  • 1-((benzylamino)(phenyl)methyl)naphthalen-2-ol

DownStream

  • dl-1,1'-bi(2-naphthyl diacetate)
  • (±)-1-(2-hydroxynapthalen-1-yl)napthalen-2-yl acetate
  • 2,2'-Bis(2-hydroxyethoxy)-1,1'-binaphthyl
  • Bis(4-nitrophenyl) carbonate
  • dinaphtho[2,1-d:1',2'-f][1,3]dioxepin-4-one
  • (r)-biphenyl-(3,4-dimethyl-1-cyclopentadienyl)-titanium(iv)-(r)-1,1'-binaphthyl-2
  • 2-ethoxy-1-(2-ethoxynaphthalen-1-yl)naphthalene
  • 2-BROMO-1,1'-BINAPHTHYL
  • (S)-N,N-Diethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (R)-[1,1'-Binaphthalene]-2,2'-diol

Customs

[ HS Code ]: 29072900

Related Compounds

  • BINOL-TF2
  • (r)-binol
  • (R,S)-BINOL
  • (S)-H8-BINOL
  • (S)-(-)-BINOL
  • (R)-(+)-BINOL
  • Isoquinolin-1-yl(7-(o-tolyl)-1,4-thiazepan-4-yl)methanone
  • 2-Cyclopropyl-1-(7-(o-tolyl)-1,4-thiazepan-4-yl)ethanone
  • 6-(2-Chloropyridin-3-yl)quinoxaline
  • 1-(2,2-Dimethylpropyl)-1H-indazole-4-carboxylic acid methyl ester
  • (S)-tert-butyl 3-(2-(3-(4-((1H-indazol-5-yl)amino)pyrimidin-2-yl)phenoxy)acetamido)pyrrolidine-1-carboxylate
  • N-(1-(2,6-Difluorophenyl)-4,5-dihydro-1H-pyrazol-3-yl)acetamide
  • tert-butyl N-[2-(2-morpholin-4-ylethoxy)phenyl]carbamate
  • 2-(2-Bromo-6-(methylthio)phenyl)acetic acid
  • (3R,5R)-3-Ethyl-5-methylmorpholine
  • 3-(4-Chloro-7H-pyrrolo[2,3-d]pyrimidin-6-yl)-2-propyn-1-ol
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