Triphenylbismuth

Suppliers

Names

[ CAS No. ]:
603-33-8

[ Name ]:
Triphenylbismuth

[Synonym ]:
Triphenylbismuthine
MFCD00014064
Bismuthine, triphenyl-
Triphenylbismuth
EINECS 210-033-4
triphenylbismuthane

Chemical & Physical Properties

[ Density]:
1,585 g/cm3

[ Boiling Point ]:
310°C

[ Melting Point ]:
78-80 °C

[ Molecular Formula ]:
C18H15Bi

[ Molecular Weight ]:
440.292

[ Flash Point ]:
242°C/14mm

[ Exact Mass ]:
440.097778

[ LogP ]:
4.46040

[ Index of Refraction ]:
1.7040 (75ºC)

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EB2980000
CHEMICAL NAME :
Bismuthine, triphenyl-
CAS REGISTRY NUMBER :
603-33-8
BEILSTEIN REFERENCE NO. :
3905930
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C18-H15-Bi
MOLECULAR WEIGHT :
440.31
WISWESSER LINE NOTATION :
R-BI-R&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
320 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 14,111,1985
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,317,1952
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01712

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H332

[ Precautionary Statements ]:
P280

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S24/25-S36/37

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
EB2980000

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • diphenylbismuthanyl bromide
  • Triphenylbismuth dichloride
  • triphenyl bismuth dibromide
  • Bismuth(III)chloride
  • phenylmagnesium bromide
  • Difluoro(triphenyl)-λ5-bismuthane
  • Bromobenzene
  • bromoanisole

DownStream

  • 1-Fluoro-4-phenoxybenzene
  • Mesityl phenyl sulfide
  • 1-Phenylpiperidine
  • m-Dibenzoylbenzene
  • 5,5-Dimethyl-2-phenyl-1,3,2-dioxaborinane
  • Diphenylborinic anhydride
  • Diphenylditelluride
  • diphenyltellurium
  • Biphenyl
  • 2-Fluorobiphenyl

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Correlation of changes in the mandible and retina/choroid vasculature of a rat model of BRONJ.

J. Craniomaxillofac. Surg. 43 , 1144-50, (2015)

Bisphosphonate-related osteonecrosis of the jaw (BRONJ) causes bones of the mandible and maxilla to become necrotic and protrude into the oral cavity. Compromised blood supply to bone is also a featur...

Cytotoxic effects of triphenylbismuth on rat thymocytes: comparisons with bismuth chloride and triphenyltin chloride.

Environ. Toxicol. 17(5) , 472-7, (2002)

The biomedical and industrial uses of organobismuth compounds have become widespread, although there is limited information concerning their cytotoxicity. Therefore, the actions of triphenylbismuth on...

Osteolytic potential of triphenyl bismuth as an alternative contrast medium in acrylic bone cement.

J. Biomed. Mater. Res. B. Appl. Biomater. 75Bth ed.,, 64, (2005)

Radiopaque cement containing barium sulfate causes significantly more bone resorption in vivo and in vitro than radiolucent cement. The aim of this study was to investigate the osteolytic potential of...


More Articles

Related Compounds

  • triphenylbismuth oxide
  • triphenylbismuth diazide
  • Difluorotriphenylbismuth
  • dinitratotriphenylbismuth
  • Triphenylbismuth Carbonate
  • triphenylbismuth diformate
  • tert-butyl N-[2-(1-hydroxy-2-methylpropan-2-yl)phenyl]carbamate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide