Triphenylbismuth

Names

[ CAS No. ]:
603-33-8

[ Name ]:
Triphenylbismuth

[Synonym ]:
Triphenylbismuthine
MFCD00014064
Bismuthine, triphenyl-
Triphenylbismuth
EINECS 210-033-4
triphenylbismuthane

Chemical & Physical Properties

[ Density]:
1,585 g/cm3

[ Boiling Point ]:
310°C

[ Melting Point ]:
78-80 °C

[ Molecular Formula ]:
C₁₈H₁₅Bi

[ Molecular Weight ]:
440.292

[ Flash Point ]:
242°C/14mm

[ Exact Mass ]:
440.097778

[ LogP ]:
4.46040

[ Index of Refraction ]:
1.7040 (75ºC)

[ Water Solubility ]:
insoluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EB2980000

CHEMICAL NAME :: Bismuthine, triphenyl-

CAS REGISTRY NUMBER :: 603-33-8

BEILSTEIN REFERENCE NO. :: 3905930

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C18-H15-Bi

MOLECULAR WEIGHT :: 440.31

WISWESSER LINE NOTATION :: R-BI-R&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 320 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 14,111,1985

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,317,1952

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01712

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H332

[ Precautionary Statements ]:
P280

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S24/25-S36/37

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
EB2980000

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

diphenylbismuthanyl bromide
Triphenylbismuth dichloride
triphenyl bismuth dibromide
Bismuth(III)chloride
phenylmagnesium bromide
Difluoro(triphenyl)-λ5-bismuthane
Bromobenzene
bromoanisole

DownStream

1-Fluoro-4-phenoxybenzene
Mesityl phenyl sulfide
1-Phenylpiperidine
m-Dibenzoylbenzene
5,5-Dimethyl-2-phenyl-1,3,2-dioxaborinane
Diphenylborinic anhydride
Diphenylditelluride
diphenyltellurium
Biphenyl
2-Fluorobiphenyl

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Correlation of changes in the mandible and retina/choroid vasculature of a rat model of BRONJ.

J. Craniomaxillofac. Surg. 43 , 1144-50, (2015)

Bisphosphonate-related osteonecrosis of the jaw (BRONJ) causes bones of the mandible and maxilla to become necrotic and protrude into the oral cavity. Compromised blood supply to bone is also a featur...

Cytotoxic effects of triphenylbismuth on rat thymocytes: comparisons with bismuth chloride and triphenyltin chloride.

Environ. Toxicol. 17(5) , 472-7, (2002)

The biomedical and industrial uses of organobismuth compounds have become widespread, although there is limited information concerning their cytotoxicity. Therefore, the actions of triphenylbismuth on...

Osteolytic potential of triphenyl bismuth as an alternative contrast medium in acrylic bone cement.

J. Biomed. Mater. Res. B. Appl. Biomater. 75Bth ed.,, 64, (2005)

Radiopaque cement containing barium sulfate causes significantly more bone resorption in vivo and in vitro than radiolucent cement. The aim of this study was to investigate the osteolytic potential of...