Triphenylamine

Suppliers

Names

[ CAS No. ]:
603-34-9

[ Name ]:
Triphenylamine

[Synonym ]:
Benzenamine, N,N-diphenyl-
MFCD00003020
N,N-Diphenylaniline
EINECS 210-035-5
N,N,N-Triphenylamine
Triphenylamine

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
365.0±11.0 °C at 760 mmHg

[ Melting Point ]:
124-128 °C(lit.)

[ Molecular Formula ]:
C18H15N

[ Molecular Weight ]:
245.318

[ Flash Point ]:
157.3±16.2 °C

[ Exact Mass ]:
245.120453

[ PSA ]:
3.24000

[ LogP ]:
5.74

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.646

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
insoluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YK2680000
CHEMICAL NAME :
Triphenylamine
CAS REGISTRY NUMBER :
603-34-9
LAST UPDATED :
199712
DATA ITEMS CITED :
15
MOLECULAR FORMULA :
C18-H15-N
MOLECULAR WEIGHT :
245.34
WISWESSER LINE NOTATION :
RNR&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,1658,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>6400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,1658,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,1658,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>6400 mg/kg
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,1658,1991 *** REVIEWS *** ACGIH TLV-TWA 5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg/m3 JAN 1993 OEL-DENMARK:TWA 5 mg/m3 JAN 1993 OEL-FINLAND:TWA 5 mg/m3;STEL 10 mg/m3;Skin JAN 1993 OEL-FRANCE:TWA 5 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO TRIPHENYL AMINE-air:10H TWA 5 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P337 + P313

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S28-S37/39-S26,37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
YK2680000

[ Packaging Group ]:
I; II; III

[ HS Code ]:
2921499090

Synthetic Route

Precursor & DownStream

Precursor

  • Iodobenzene
  • Diphenylamine
  • Bromobenzene
  • Chlorobenzene
  • N-Phenyl-1-naphthalenamine
  • Silanamine, 1,1,1-trimethyl-N,N-diphenyl-
  • 2-trimethylsilylphenyl triflate
  • Phenylisocyanate

DownStream

  • 4-Nitro-N,N-diphenylaniline
  • Tris(4-nitrophenyl)amine
  • BIS-(4-NITROPHENYL)PHENYLAMINE
  • Bis-(4-nitrophenyl)-2-nitrophenylamine
  • 2-NITROPHENYL DIPHENYLAMINE
  • 4-BROMOTRIPHENYLAMINE
  • tris(4-iodophenyl)amine
  • 4,4'-(Phenylimino)dibenzoic acid
  • Tris-(4-ethynyl-phenyl)-amine

Customs

[ HS Code ]: 2921499090

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • Triphenylamine-d15
  • 4,4'-Diaminotriphenylamine
  • 4,4'-Dimethyltriphenylamine
  • 4,4-Dimethoxy-triphenylamine
  • Triphenylamine-4-boronic Acid
  • .4,4'-diphenyl-triphenylamine