Triphenylstibine
Suppliers
Names
[ CAS No. ]:
603-36-1
        
[ Name ]:
 Triphenylstibine
        
[Synonym ]:
                
                MFCD00003000
                
                
            
                
                TRIPHENYLSTIBANE
                
                
            
                
                Triphenylstibine
                
                
            
                
                EINECS 210-037-6
                
                
            
                
                Stibine, triphenyl-
                
                
                
                
    
Chemical & Physical Properties
[ Density]:
1.43
            
[ Boiling Point ]:
377ºC
            
[ Melting Point ]:
52-55ºC
            
[ Molecular Formula ]:
C18H15Sb
            
[ Molecular Weight ]:
353.072
            
[ Flash Point ]:
109ºC
            
[ Exact Mass ]:
352.021210
            
[ LogP ]:
4.46040
            
[ Index of Refraction ]:
1.6948 (42ºC)
            
[ Stability ]:
Stable. Incompatible with strong oxidizing agents.
            
[ Water Solubility ]:
INSOLUBLE
            
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
 - WJ1400000
 
- CHEMICAL NAME :
 - Stibine, triphenyl-
 
- CAS REGISTRY NUMBER :
 - 603-36-1
 
- BEILSTEIN REFERENCE NO. :
 - 3608108
 
- LAST UPDATED :
 - 199712
 
- DATA ITEMS CITED :
 - 32
 
- MOLECULAR FORMULA :
 - C18-H15-Sb
 
- MOLECULAR WEIGHT :
 - 353.08
 
- WISWESSER LINE NOTATION :
 - R-SB-R&R
 
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
 - LD50 - Lethal dose, 50 percent kill
 
- ROUTE OF EXPOSURE :
 - Oral
 
- SPECIES OBSERVED :
 - Rodent - rat
 
- DOSE/DURATION :
 - 183 mg/kg
 
- TOXIC EFFECTS :
 - Details of toxic effects not reported other than lethal dose value
 
- REFERENCE :
 - 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1280,1986
 
- TYPE OF TEST :
 - LD50 - Lethal dose, 50 percent kill
 
- ROUTE OF EXPOSURE :
 - Intraperitoneal
 
- SPECIES OBSERVED :
 - Rodent - rat
 
- DOSE/DURATION :
 - 168 mg/kg
 
- TOXIC EFFECTS :
 - Details of toxic effects not reported other than lethal dose value
 
- REFERENCE :
 - AMRL** Aerospace Medical Research Laboratory Report. (Aerospace Technical Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433) Volume(issue)/page/year: TR-74-78,1974
 
- TYPE OF TEST :
 - LD50 - Lethal dose, 50 percent kill
 
- ROUTE OF EXPOSURE :
 - Oral
 
- SPECIES OBSERVED :
 - Rodent - mouse
 
- DOSE/DURATION :
 - 650 mg/kg
 
- TOXIC EFFECTS :
 - Details of toxic effects not reported other than lethal dose value
 
- REFERENCE :
 - AMRL** Aerospace Medical Research Laboratory Report. (Aerospace Technical Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433) Volume(issue)/page/year: TR-74-78,1974
 
- TYPE OF TEST :
 - LDLo - Lowest published lethal dose
 
- ROUTE OF EXPOSURE :
 - Intraperitoneal
 
- SPECIES OBSERVED :
 - Rodent - mouse
 
- DOSE/DURATION :
 - 500 mg/kg
 
- REFERENCE :
 - CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,229,1954 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,15,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-FINLAND:.TWA (0.5 mg(Sb)/m3) JAN 1993 OEL-FRANCE:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ANTIMONY-air:10H TWA 0.5 mg(Sb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0487 No. of Facilities: 16 (estimated) No. of Industries: 4 No. of Occupations: 8 No. of Employees: 724 (estimated) No. of Female Employees: 126 (estimated)
 
Safety Information
[ Symbol ]:
                
                
                GHS07, GHS09
            
[ Signal Word ]: 
Warning
            
[ Hazard Statements ]:
 H302-H332-H411
            
[ Precautionary Statements ]:
 P273
            
[ Personal Protective Equipment ]:
 dust mask type N95 (US);Eyeshields;Faceshields;Gloves
            
[ Hazard Codes ]:
 Xn:Harmful
            
[ Risk Phrases ]:
 R20/22;R51/53
            
[ Safety Phrases ]:
 S61
            
[ RIDADR ]: 
UN 3467
            
[ WGK Germany ]: 
2
            
[ RTECS ]: 
WJ1400000
            
[ Packaging Group ]:
 III
            
[ Hazard Class ]:
6.1(b)
            
[ HS Code ]:
 29310095
            
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 29310095