Triphenylstibine

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Names

[ CAS No. ]:
603-36-1

[ Name ]:
Triphenylstibine

[Synonym ]:
MFCD00003000
TRIPHENYLSTIBANE
Triphenylstibine
EINECS 210-037-6
Stibine, triphenyl-

Chemical & Physical Properties

[ Density]:
1.43

[ Boiling Point ]:
377ºC

[ Melting Point ]:
52-55ºC

[ Molecular Formula ]:
C18H15Sb

[ Molecular Weight ]:
353.072

[ Flash Point ]:
109ºC

[ Exact Mass ]:
352.021210

[ LogP ]:
4.46040

[ Index of Refraction ]:
1.6948 (42ºC)

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
INSOLUBLE

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WJ1400000
CHEMICAL NAME :
Stibine, triphenyl-
CAS REGISTRY NUMBER :
603-36-1
BEILSTEIN REFERENCE NO. :
3608108
LAST UPDATED :
199712
DATA ITEMS CITED :
32
MOLECULAR FORMULA :
C18-H15-Sb
MOLECULAR WEIGHT :
353.08
WISWESSER LINE NOTATION :
R-SB-R&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
183 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1280,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
168 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMRL** Aerospace Medical Research Laboratory Report. (Aerospace Technical Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433) Volume(issue)/page/year: TR-74-78,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
650 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMRL** Aerospace Medical Research Laboratory Report. (Aerospace Technical Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433) Volume(issue)/page/year: TR-74-78,1974
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/kg
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,229,1954 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,15,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-FINLAND:.TWA (0.5 mg(Sb)/m3) JAN 1993 OEL-FRANCE:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ANTIMONY-air:10H TWA 0.5 mg(Sb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0487 No. of Facilities: 16 (estimated) No. of Industries: 4 No. of Occupations: 8 No. of Employees: 724 (estimated) No. of Female Employees: 126 (estimated)

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H332-H411

[ Precautionary Statements ]:
P273

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/22;R51/53

[ Safety Phrases ]:
S61

[ RIDADR ]:
UN 3467

[ WGK Germany ]:
2

[ RTECS ]:
WJ1400000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
29310095

Synthetic Route

Precursor & DownStream

Precursor

  • Antimony trichloride
  • 2-Amino-2,4,6-cycloheptatrien-1-one
  • Dichloro(triphenyl)stiborane
  • Lithium
  • Diacetoxy(triphenyl)stiborane
  • Bromo(tetraphenyl)stiborane
  • acrylic acid methyl ester
  • Antimony

DownStream

  • Triphenylstibine oxide
  • 2-Phenylacetophenone
  • (S)-(+)-1,2-DIPHENYLETHANOL
  • 5,5-Dimethyl-2-phenyl-1,3,2-dioxaborinane
  • anilinomethanedithioate; phenylantimony
  • Stibine,[(dimethylthiocarbamoyl)thio]diphenyl- (7CI,8CI)
  • Stibine,[(diphenylthiocarbamoyl)thio]diphenyl- (7CI,8CI)
  • pentakis-phenyl-λ5-stibane
  • Triphenylbismuth
  • Antimony,chlorotetraphenyl-, (TB-5-12)-

Customs

[ HS Code ]: 29310095


Related Compounds

  • Triphenylstibine oxide
  • Triphenylstibine sulfide
  • .Pt(triphenylstibine)2Cl2
  • platinum tris(triphenylstibine)
  • triphenylstibine hydroxychloride
  • (triphenylstibine)tricarbonylchromium
  • tert-butyl N-(5-bromo-3-iodo-2-methylphenyl)carbamate
  • Tert-butyl 4-(hydroxymethyl)-1-(2,2,2-trifluoroacetamido)-3-oxaspiro[bicyclo[2.1.1]hexane-2,4'-piperidine]-1'-carboxylate
  • benzyl N-{4-oxo-4H,5H,6H-cyclopenta[d][1,3]thiazol-2-yl}carbamate
  • benzyl N-[2-(6-fluoropyridin-2-yl)propyl]carbamate
  • benzyl N-(2-cyanoethyl)-N-(1,3,4-thiadiazol-2-yl)carbamate
  • benzyl N-methyl-N-[2-oxo-1-(prop-2-en-1-yl)pyrrolidin-3-yl]carbamate
  • [1-(4-methoxybutan-2-yl)-5-methyl-1H-1,2,3-triazol-4-yl]methanamine
  • 5-[(1H-pyrazol-1-yl)methyl]-1,3-oxazinan-2-one
  • tert-butyl N-(5-bromo-6-oxo-1,6-dihydropyridin-3-yl)carbamate
  • Benzyl 8-fluoro-8-(hydroxymethyl)-6-azaspiro[3.4]octane-6-carboxylate
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