2-Methyl-3-nitroaniline

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Names

[ CAS No. ]:
603-83-8

[ Name ]:
2-Methyl-3-nitroaniline

[Synonym ]:
2-methyl-3-nitro-aniline
MFCD00007731
Benzenamine,2-methyl-3-nitro
2-Amino-6-nitrotoluene
3-NITRO-O-TOLUIDINE
2-methyl-3-nitrobenzeneamine
o-Toluidine,3-nitro
1-Amino-2-methyl-3-nitrobenzene
EINECS 210-059-6
2-nitro-6-aminotoluene
2-methyl-3-nitro-benzenamine

Chemical & Physical Properties

[ Density]:
1.378

[ Boiling Point ]:
305 °C(lit.)

[ Melting Point ]:
88-90 °C(lit.)

[ Molecular Formula ]:
C7H8N2O2

[ Molecular Weight ]:
152.15100

[ Flash Point ]:
305°C

[ Exact Mass ]:
152.05900

[ PSA ]:
71.84000

[ LogP ]:
2.58980

[ Index of Refraction ]:
1.475

[ Water Solubility ]:
<0.1 g/100 mL at 23 ºC

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XU8200000
CHEMICAL NAME :
o-Toluidine, 3-nitro-
CAS REGISTRY NUMBER :
603-83-8
BEILSTEIN REFERENCE NO. :
0388393
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C7-H8-N2-O2
MOLECULAR WEIGHT :
152.17
WISWESSER LINE NOTATION :
WNR CZ B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TEST SYSTEM :
Rodent - rat
DOSE/DURATION :
183 ug/kg
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 301,79,1993

Safety Information

[ Symbol ]:

GHS06, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H373-H411

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R23/24/25;R33;R51/53

[ Safety Phrases ]:
S28-S36/37-S45-S61-S28A

[ RIDADR ]:
UN 2660 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
XU8200000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29214300

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,6-Dinitrotoluene
  • 4-amino-2,6-dinitrotoluene
  • o-Toluidine
  • 1H-Isoindole-1,3(2H)-dione,2-(2-methylphenyl)-
  • Ammonia
  • Ethanol
  • Hydrochloric acid
  • ethyl acetate
  • hydrogen sulfide
  • Sulfuric acid

DownStream

  • 4-Fluoro-1H-indazole
  • Phenol, methylnitro-
  • 3-Amino-2-methylphenol
  • 2-(2-Bromo-6-nitrophenyl)acetic Acid
  • 2,6-Dinitrotoluene
  • 4-Nitroindole
  • 3-Fluoro-2-methylaniline
  • 2-methyl-3-nitroanisole
  • 2,6-Difluorotoluene
  • 2-Fluoro-6-nitrobenzoic acid

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Voltammetric determination of Ioxynil and 2-methyl-3-nitroaniline using C(18) modified carbon paste electrodes.

Anal. Bioanal. Chem 356(3-4) , 279-83, (1996)

The stripping voltammetric behaviour of Ioxynil and 2-methyl-3-nitroaniline has been studied by means of a C(18) modified carbon paste electrode. The analytes are preconcentrated under open-circuit co...

Microbial transformation of nitroaromatics in surface soils and aquifer materials.

Appl. Environ. Microbiol. 60(6) , 2170-5, (1994)

Microorganisms indigenous to surface soils and aquifer materials collected at a munitions-contaminated site transformed 2,4,6-trinitrotoluene (TNT), 2,4-dinitrotoluene (2,4-DNT), and 2,6-dinitrotoluen...

[Different frequency of induction of liver tumors in reciprocal murine hybrids].

Dokl. Akad. Nauk. 348(1) , 129-31, (1996)


More Articles

Related Compounds

  • 4-Iodo-2-methyl-3-nitroaniline
  • 5-iodo-2-methyl-3-nitroaniline
  • 4-bromo-2-methyl-3-nitroaniline
  • 5-Bromo-2-methyl-3-nitroaniline
  • 5-Fluoro-2-methyl-3-nitroaniline
  • 5-Chloro-2-methyl-3-nitroaniline
  • 2-(Difluoromethyl)-3-methoxy-4-(trifluoromethyl)pyridine-5-acetonitrile
  • 2-(Difluoromethyl)-5-methyl-3-nitropyridine-6-sulfonamide
  • 2-(Difluoromethyl)-3-methoxy-5-nitropyridine-4-acetonitrile
  • 2'-(Difluoromethoxy)-5'-(trifluoromethoxy)propiophenone
  • 2-(Difluoromethyl)-6-hydroxy-3-methylpyridine-5-carboxylic acid
  • 2-(Difluoromethyl)-3-nitropyridine-5-carboxaldehyde
  • 2-(Difluoromethyl)-5-methylpyridine-4-carboxylic acid
  • 2-(Difluoromethyl)-6-methoxy-3-(trifluoromethoxy)pyridine-4-acetic acid
  • 2-(Difluoromethyl)-6-methoxy-4-methylpyridine-3-carboxylic acid
  • 2-(Difluoromethyl)-6-hydroxy-5-methoxy-3-(trifluoromethoxy)pyridine
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