3,3-Dimethoxy-1-propene

Names

[ Name ]:
3,3-Dimethoxy-1-propene

[Synonym ]:
1-Propene, 3,3-dimethoxy-
3,3-Dimethoxy-1-propene
EINECS 227-936-4
3,3-Dimethoxyprop-1-ene
MFCD00008632
AcroleinDimethylAcetal

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
89.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₁₀O₂

[ Molecular Weight ]:
102.132

[ Flash Point ]:
-2.8±0.0 °C

[ Exact Mass ]:
102.068077

[ PSA ]:
18.46000

[ LogP ]:
0.65

[ Vapour Pressure ]:
66.0±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.392

[ Storage condition ]:
2-8°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UC8500000

CHEMICAL NAME :: 1-Propene, 3,3-dimethoxy-

CAS REGISTRY NUMBER :: 6044-68-4

BEILSTEIN REFERENCE NO. :: 1700037

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C5-H10-O2

MOLECULAR WEIGHT :: 102.15

WISWESSER LINE NOTATION :: 1OYO1&1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 56 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03553

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S16-S23-S24/25-S29-S33

[ RIDADR ]:
UN 3384 6.1/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
UC8500000

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2911000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Methanol
acrolein
Trimethyl orthoformate
Allyl Butyl Ether
Allyl ether
Propane,1,1,3-trimethoxy-
1-Methoxyallene
3-Chloropropionaldehyde Dimethyl Acetal
Hydrochloric acid
leucoline

DownStream

Ethyl methoxyacetate
methyl 2-carbomethoxy-2,5-dimethoxy-(E)-4-pentenoate
dimethyl 2-methoxy-2-(1-methoxyprop-2-enyl)propanedioate
4-Pentenoic acid, 2,5-dimethoxy-, ethyl ester, (Z)
ethyl 2,5-dimethoxypent-4-enoate
ethyl 2-(dimethoxymethyl)-1-cyclopropanecarboxylate
ethyl (1R,2R)-2-(dimethoxymethyl)cyclopropane-1-carboxylate
3-Bromo-1,1-dimethoxypropane
3-methoxypent-1-ene

Customs

[ HS Code ]: 2911000000

[ Summary ]:
2911000000 acetals and hemiacetals, whether or not with other oxygen function, and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Palladium-catalyzed copolymerization of ethene with acrolein dimethyl acetal: catalyst action and deactivation.

J. Am. Chem. Soc. 126(39) , 12246-7, (2004)

Acrolein dimethyl acetal (ADMA) can be copolymerized with ethene using a cationic alpha-diimine palladium chelate catalyst to yield branched copolymers. Catalyst deactivation occurs via methanol elimi...

An expeditious synthesis of 4-hydroxy-2E-nonenal (4-HNE), its dimethyl acetal and of related compounds.

Chem. Phys. Lipids 150(2) , 239-43, (2007)

The facile one step synthesis of 4-hydroxy-2E-nonenal and its dimethyl acetal via a cross-metathesis reaction between commercially available octen-3-ol and acrolein or its dimethyl acetal is reported....