(S)-Methyl 2,2-dimethyl-1,3-dioxolane-4-carboxylate

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Names

[ CAS No. ]:
60456-21-5

[ Name ]:
(S)-Methyl 2,2-dimethyl-1,3-dioxolane-4-carboxylate

[Synonym ]:
Methyl (4S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate
(S)-2,2-Dimethyl-[1,3]dioxolane-4-carboxylic acid methyl ester
1,3-Dioxolane-4-carboxylic acid, 2,2-dimethyl-, methyl ester, (4S)-
Methyl (S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate
MFCD00066526

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
196.2±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H12O4

[ Molecular Weight ]:
160.168

[ Flash Point ]:
78.3±0.0 °C

[ Exact Mass ]:
160.073563

[ PSA ]:
44.76000

[ LogP ]:
0.61

[ Vapour Pressure ]:
0.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.422

[ Storage condition ]:
2~8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
23-24/25

[ WGK Germany ]:
3.0

[ HS Code ]:
2932999099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-hydroxyethanone
  • methyl (S)-glycerate
  • 2,2-Dimethoxypropane
  • diazomethane
  • (S)-2,2-Dimethyl-1,3-dioxolane-4-carboxylicacid
  • 2-methyoxypropene
  • Potassium(S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate
  • methyl iodide
  • Methyl 2,3-dihydroxypropanoate
  • 5,6-0,0-isopropylidene-L-ascorbic acid

DownStream

  • (S)-2,2-Dimethyl-1,3-dioxolane-4-carbaldehyde
  • (S)-2,2-Dimethyl-1,3-dioxolane-4-carboxylicacid
  • Methanol
  • methyl (S)-glycerate
  • (r)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane
  • (R)-(-)-Solketal

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Studies on the synthesis of (-)-gymnodimine. Subunit synthesis and coupling.

J. Org. Chem. 72 , 1717, (2007)

Two principal subunits of the marine algal toxin (-)-gymnodimine were synthesized. A trisubstituted tetrahydrofuran representing C10-C18 of the toxin was prepared via a highly stereoselective iodine-m...


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Related Compounds

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  • tert-butyl N-(2-chloro-1,7-naphthyridin-4-yl)carbamate
  • tert-butyl 4-fluoro-7-nitro-1H-indazole-1-carboxylate
  • tert-butyl N-[(4,5-dichloro-1-methyl-1H-pyrazol-3-yl)methyl]-N-methylcarbamate
  • 1-bromo-3-chloro-5H,6H,7H-pyrrolo[1,2-c]imidazole
  • Prop-2-en-1-yl 3,3-diethenylmorpholine-4-carboxylate
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}(4-fluoro-2-nitrophenyl)amino)propanoic acid
  • tert-butyl N-[2-(fluorosulfonyl)pyridin-3-yl]carbamate
  • 4-(Piperidin-2-yl)-1-(trifluoromethyl)isoquinoline
  • (3R,5S)-3,5-dimethoxymorpholine
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