Cupric acetate monohydrate

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Names

[ CAS No. ]:
6046-93-1

[ Name ]:
Cupric acetate monohydrate

[Synonym ]:
MFCD00149570
copper,diacetate,hydrate
EINECS 205-553-3
Cupric acetate monohydrate

Chemical & Physical Properties

[ Density]:
1.882

[ Boiling Point ]:
117.1ºC at 760 mmHg

[ Melting Point ]:
115ºC (dec.)

[ Molecular Formula ]:
C4H8CuO5

[ Molecular Weight ]:
199.64900

[ Flash Point ]:
40ºC

[ Exact Mass ]:
198.96700

[ PSA ]:
89.49000

[ Vapour density ]:
6.9 (vs air)

[ Stability ]:
Stable. Incompatible with oxidizing agents.

[ Water Solubility ]:
72 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AG3500000
CHEMICAL NAME :
Acetic acid, copper(2+) salt, monohydrate
CAS REGISTRY NUMBER :
6046-93-1
LAST UPDATED :
199701
DATA ITEMS CITED :
34
MOLECULAR FORMULA :
C4-H6-O4.Cu.H2-O
MOLECULAR WEIGHT :
199.66
WISWESSER LINE NOTATION :
OV1 2 &-CU- &QH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
710 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 14,111,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
5 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Gastrointestinal - changes in structure or function of salivary glands Gastrointestinal - nausea or vomiting
REFERENCE :
JANSAG Journal of Animal Science. (American Soc. of Animal Science, 309 W. Clark St., Champaign, IL 61820) V.1- 1942- Volume(issue)/page/year: 55,337,1982 *** REVIEWS *** TOXICOLOGY REVIEW 85DHAX "Medical and Biologic Effects of Environmental Pollutants Series," Washington, DC, National Academy of Sciences, 1972-77 Volume(issue)/page/year: Cu,56,1977 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-BELGIUM:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-DENMARK:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FINLAND:TWA 1 mg(Cu)/m3 JAN 1993 OEL-FRANCE:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust) JAN 1993 OEL-GERMANY:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-GERMANY:TWA 1 mg(Cu)/m3 JAN 1993 OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4 mg(Cu)/m3 (dust) JAN 1993 OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 02 mg(Cu)/m3 (fume) JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dust) JAN 1993 OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN 1993 OEL-POLAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-RUSSIA:STEL 0.5 ppm (1 mg(Cu)/m3) (dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWEDEN:TWA 1 mg(Cu)/m3 (total dust) JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-SWITZERLAND:TWA 1 mg(Cu)/m3;STEL 1 mg(Cu)/m3 JAN 1993 OEL-THAILAND:TWA 0.1 mg(Cu)/m3 (fume) JAN 1993 OEL-THAILAND:TWA 1 mg(Cu)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.2 mg(Cu)/m3 (fume) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Cu)/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4554 No. of Facilities: 1064 (estimated) No. of Industries: 3 No. of Occupations: 8 No. of Employees: 6695 (estimated) No. of Female Employees: 2725 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314-H410

[ Precautionary Statements ]:
P260-P280-P301 + P312 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;

[ Risk Phrases ]:
R22;R36/37/38;R50/53

[ Safety Phrases ]:
36/37/39-60-61-36-26

[ RIDADR ]:
UN 9106/3077

[ WGK Germany ]:
3

[ RTECS ]:
AG3500000

[ Hazard Class ]:
9.0

[ HS Code ]:
2915299011

Synthetic Route

Precursor & DownStream

Precursor

  • Sodium acetate
  • ch3cho
  • Ethanol
  • acetic acid
  • Copper(II) acetate
  • Cupric hydroxide
  • acetic acid , acidic copper (II)-acetate
  • Calcium acetate
  • Copper sulfate pentahydrate

DownStream

  • COPPER(II) 1,4,8,11,15,18,22,25-OCTA- BUTOXYPHTHALOCYANINE
  • 1,2-BIS(3-METHOXYPHENYL)ETHANE-1,2-DIONE
  • dicopper,pyridine,tetraacetate
  • Copper, [2-(hydroxy-kO)benzoato-kO](8-quinolinolato-kN1,kO8)-
  • Cupric hydroxide
  • Copper(1+) sulfidocopper
  • Cupric oxalate
  • COPPER(I) ACETATE
  • Water

Customs

[ HS Code ]: 2915299011

[ Summary ]:
2915299011 copper(ii) acetate。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。Lowest tariff:5.5%。General tariff:50.0%

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