Methyl 2-benzoylbenzoate

Names

[ CAS No. ]:
606-28-0

[ Name ]:
Methyl 2-benzoylbenzoate

[Synonym ]:
MFCD00017187
Methyl 2-benzoylbenzoate
EINECS 210-112-3
o-Benzoyl Benzomethoxycarbonyl(OBM)
Benzoic acid, 2-benzoyl-, methyl ester

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
351.5±15.0 °C at 760 mmHg

[ Melting Point ]:
48-53 °C(lit.)

[ Molecular Formula ]:
C₁₅H₁₂O₃

[ Molecular Weight ]:
240.254

[ Flash Point ]:
154.4±20.4 °C

[ Exact Mass ]:
240.078644

[ PSA ]:
43.37000

[ LogP ]:
2.61

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.574

MSDS

Safety Information

[ Symbol ]:

GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H410

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
N: Dangerous for the environment;

[ Risk Phrases ]:
R50/53

[ Safety Phrases ]:
S60-S61

[ RIDADR ]:
UN 3077 9/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
9.0

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

tert-Butyl Hydroperoxide
2-Benzoylbenzoic acid
Methyl 2-iodobenzoate
Carbon monooxide-molybdenum (6:1)
Phenylboronic acid
3-Methoxy-3-phenyl-2-benzofuran-1(3H)-one
methyl 2-(chlorocarbonyl)benzoate
benzene
methyl iodide
Methanol

DownStream

2-(Benzoylamino)benzoic acid
Bentranil
1(3H)-Isobenzofuranone,3-phenyl-
(2-hydroxymethylphenyl)phenylmethanol
2-Benzyl benzoic acid methyl ester
2-benzoylbenzamide
2-amino-4-(2-benzoylphenyl)pyrimidine-5-carbonitrile
3-phenyl-2,3-dihydroisoindol-1-one
Benzoic acid,2-benzoyl-, ethyl ester
[2-[hydroxy(diphenyl)methyl]phenyl]-phenylmethanone

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Identification of print-related contaminants in food packaging.

Food Addit. Contam. Part A. Chem. Anal. Control. Expo. Risk Assess. 33 , 518-29, (2016)

Since the UV ink photoinitiator (PI) isopropylthioxanthone (ITX) was discovered in packaged milk, studies of print contamination have focused primarily on PIs but have also included amine synergists. ...

Photoinitiator-Initiated Estrogenic Activity in Human Breast Cancer Cell Line MCF-7.

J. Toxicol. Environ. Health A 78 , 1450-60, (2015)

A recent in vitro study reported that the photoinitiator 2-isopropylthioxanthone (2-ITX) is an endocrine-disrupting compound (EDC). However, it is not clear whether other photoinitiators such as 1-hyd...

Stereoselective synthesis of 3-substituted phtalides via asymmetric transfer hydrogenation using well-defined ruthenium catalysts under neutral conditions. Everaere K, et al.

Tetrahedron Lett. 42(10) , 1899-1901, (2001)

methyl 2-[2-(2-methoxy-2-oxoethyl)phenyl]acetate
methyl 2-(3-oxobutyl)benzoate
methyl 2-(1-ethyl-2-oxocyclohex-3-en-1-yl)acetate
methyl 2-(2',4'-dichloro-5-methoxy-[1,1'-biphenyl]-3-yl)acetate
methyl 2-phenyldiazenyl-2-(triphenyl-λ5-phosphanylidene)acetate
methyl 2-chloro-2-[(4-nitrophenyl)hydrazinylidene]acetate