2-(Benzyloxy)acetaldehyde

Names

[ Name ]:
2-(Benzyloxy)acetaldehyde

[Synonym ]:
Acetaldehyde, 2-(phenylmethoxy)-
EINECS 262-349-7
MFCD00191779
(Benzyloxy)acetaldehyde
benzyloxyacetaldehyde

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
212.4±15.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₁₀O₂

[ Molecular Weight ]:
150.174

[ Flash Point ]:
80.2±13.9 °C

[ Exact Mass ]:
150.068085

[ PSA ]:
26.30000

[ LogP ]:
1.56

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.507

[ Storage condition ]:
Refrigerator (+4°C)

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P337 + P313

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26-S37-S39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2912499000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

CIS-1,4-DIBENZYLOXY-2-BUTENE
[(2,2-Diethoxyethoxy)methyl]benzene
meso-1,4-bis(benzyloxy)butane-2,3-diol
2-(Benzyloxy)ethanol
1-o-benzyl-rac-glycerol
[(Allyloxy)methyl]benzene
(E)-4-[(Benzyl)oxy]-2-buten-1-ol
Dichloromethane

DownStream

(2S,3S)-1-(2-METHYLAMINO-2-PHENYL-ETHYL)-PYRROLIDIN-3-OL
(R)-3-Hydroxy-gamma-butyrolactone
UNII:0M94O5FN60
1-(Benzyloxy)-2-butanol
2-(BENZYLOXY)-1-CYCLOPROPYLETHANOL
BENZYL 2-(BENZYLOXY)ACETATE
1-(Benzyloxy)acetone
2-(Benzyloxy)ethanol
Miglitol
methyl 2-methyl-4-phenylmethoxybut-2-enoate

Customs

[ HS Code ]: 2912499000

[ Summary ]:
2912499000. other aldehyde-ethers, aldehyde-phenols and aldehydes with other oxygen function. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Recombinant production of serine hydroxymethyl transferase from Streptococcus thermophilus and its preliminary evaluation as a biocatalyst.

Appl. Microbiol. Biotechnol. 68(4) , 489-97, (2005)

The glyA gene encoding a serine hydroxymethyl transferase (SHMT) with threonine aldolase activity was isolated from Streptococcus thermophilus YKA-184 chromosomal DNA. This aldolase is a pyridoxal 5'-...

C2-symmetric copper (II) complexes as chiral Lewis acids. Scope and mechanism of catalytic enantioselective aldol additions of enolsilanes to (benzyloxy) acetaldehyde. Evans DA, et al.

J. Am. Chem. Soc. 121(4) , 669-685, (1999)

A short enantioselective synthesis of 1-deoxy-L-xylulose by antibody catalysis. Shabat D, et al.

Tetrahedron Lett. 40(8) , 1437-40, (1999)

(2-benzyloxy-ethoxy)-acetaldehyde
2-benzyloxy-6-nitrophenyl acetaldehyde
2-benzyloxy-6-nitrophenyl acetaldehyde dimethyl acetal
2-(benzyloxy)-2-(4-methoxyphenyl)acetaldehyde
2-(benzyloxy)-2-(4-chlorophenyl)acetaldehyde
2-(Benzyloxy)-5-bromopyrimidine
Benzoic acid, 3-(aminomethyl)-2-cyano-4-(trifluoromethyl)-, ethyl ester
I+/--[(1,2-Dioxopropyl)amino]-N-methylbenzenepropanamide
3-Bromo-N-(2,2-difluoropropyl)benzenamine
1,6-Naphthyridine, 2-(2-methylphenyl)-
1,1-Dimethylethyl 1-[(4-methylphenyl)sulfonyl]-1H-pyrrole-2-carboxylate
Methyl 2,2-dimethyl[1,1a(2)-bicyclopropyl]-1-carboxylate
Benzoic acid, 4-fluoro-, 2-(diethylamino)-1-(fluoromethyl)ethyl ester
1-[rel-(1R,2R,5S,6S)-3-Benzyl-2-methyl-3-azabicyclo[3.1.0]hexan-6-yl]methanamine
Spiro[diaziridine-3,6a(2)(4a(2)H)-pyrano[3,2-d][1,3]dioxin]
Phosphoric acid, diethyl ester, ester with N-ethyl-4-hydroxyphthalimide

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