(2S)-3-Chlorpropan-1,2-diol

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Names

[ CAS No. ]:
60827-45-4

[ Name ]:
(2S)-3-Chlorpropan-1,2-diol

[Synonym ]:
(S)-3-Chloro-1,2-propanediol
1,2-Propanediol, 3-chloro-, (S)-
EINECS 202-492-4
Q1YQ1G &&S Form
(2S)-3-chloropropane-1,2-diol
(2S)-3-Chloro-1,2-propanediol
1,2-Propanediol, 3-chloro-, (2S)-
MFCD00210270
(2S)-3-Chlorpropan-1,2-diol
(S)-(+)-3-chloro-1,2-propanediol
S-2-Chloro-1,2-propanediol

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
213.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C3H7ClO2

[ Molecular Weight ]:
110.539

[ Flash Point ]:
113.3±21.8 °C

[ Exact Mass ]:
110.013458

[ PSA ]:
40.46000

[ LogP ]:
-0.76

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.474

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TY4202300
CHEMICAL NAME :
1,2-Propanediol, 3-chloro-, (S)-
CAS REGISTRY NUMBER :
60827-45-4
LAST UPDATED :
198910
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C3-H7-O2
MOLECULAR WEIGHT :
75.10

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
45500 ug/kg
SEX/DURATION :
male 14 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females)
REFERENCE :
JRPFA4 Journal of Reproduction and Fertility. (Biochemical Soc. Book Depot, POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK) V.1- 1960- Volume(issue)/page/year: 51,105,1977

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H312-H318

[ Precautionary Statements ]:
P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R21;R23/25;R36/37/38;R62;R68

[ Safety Phrases ]:
S26-S28-S39-S45-S36/37/39

[ RIDADR ]:
UN 2689 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
TY4202300

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2905590090

Synthetic Route

Precursor & DownStream

Precursor

  • Epichlorohydrin
  • 1-chloro-3-hydroxypropan-2-one
  • (S)-(+)-Epichlorhydrin
  • ALLYL CHLORIDE
  • (S)-1,2-Diacetoxy-3-chloropropane
  • 3-Chloro-1,2-propanediol
  • 1-CHLOROMETHYL-1,2-ETHANEDIOL DIACETATE

DownStream

  • (5r)-3-(4-bromo-3-fluorophenyl)-5-hydroxymethyloxazolidin-2-one
  • (±)-Glycidol
  • (2R)-(-)-Glycidyl tosylate
  • (S)-Glycidyl nosylate

Customs

[ HS Code ]: 2905590090

[ Summary ]:
2905590090 other halogenated, sulphonated, nitrated or nitrosated derivatives of acyclic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Complete detoxification of tris(1,3-dichloro-2-propyl) phosphate by mixed two bacteria, Sphingobium sp. strain TCM1 and Arthrobacter sp. strain PY1.

J. Biosci. Bioeng. 113(1) , 79-83, (2012)

Tris(1,3-dichloro-2-propyl) phosphate (TDCPP), a flame retardant, is regarded as a potentially toxic and persistent environmental contaminant. We previously isolated a TDCPP-degrading bacterium, Sphin...

Passage of MHPG from plasma to CSF in a non-human primate.

Rev. Med. Chir. Soc. Med. Nat. Iasi. 115(4) , 1278-82, (2011)

In experimental protocols with humans and non-human primates, cerebrospinal fluid (CSF) concentrations of 3-methoxy-4-hydroxyphenylethylene glycol (MHPG), the predominant end-product of norepinephrine...

Fatty acid esters of monochloropropanediol (MCPD) and glycidol in refined edible oils.

Food Addit. Contam. Part A. Chem. Anal. Control. Expo. Risk Assess. 30(1) , 46-51, (2013)

Recently, fatty acid esters of monochloropropanediol (MCPD) and that of glycidol have been reported in refined edible oils. Since then a wealth of research has been published on the factors influencin...


More Articles


Related Compounds

  • (2S)-3-heptadecoxypropane-1,2-diol
  • (2S)-3,3-dichloropropane-1,2-diol
  • (2S)-3-(4-phenylmethoxyphenyl)propane-1,2-diol
  • (2S)-3-(4-methoxyphenoxy)propane-1,2-diol
  • (2S)-3-(12-bromododecoxy)propane-1,2-diol
  • (2S)-3-(12-hydroxydodecoxy)propane-1,2-diol
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 5-chloro-2-ethylpyrimidine-4-carboxylate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 4-tert-butyl-1,3-thiazole-5-carboxylate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 2-cyclohexyl-2-methylpropanoate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 5H,6H,7H,8H-imidazo[1,2-a]pyridine-8-carboxylate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl furo[3,2-c]pyridine-2-carboxylate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 3-cyano-4-fluorobenzoate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl octahydroindolizine-3-carboxylate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 2,6-difluoro-4-methylbenzoate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 2-[(tert-butyldimethylsilyl)oxy]acetate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 7-methylquinoxaline-6-carboxylate
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