Dimethyl methylmalonate

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Names

[ CAS No. ]:
609-02-9

[ Name ]:
Dimethyl methylmalonate

[Synonym ]:
dimethyl methyl-malonate
Propanedioic acid, 2-methyl-, dimethyl ester
dimethyl malonate
dimethyl methylpropanedioate
Dimethyl 2-methylmalonate
Propanedioic acid, methyl-, dimethyl ester
Propanedioic acid,methyl-,dimethyl ester
Malonic acid, methyl-, dimethyl ester (8CI)
MFCD00075185
EINECS 210-173-6
methyl malonic acid methyl ester
methylmalonic acid dimethyl ester
Dimethyl methylmalonate
Malonic acid,methyl-,dimethyl ester
CH3CH(CO2Me)2

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
173.6±8.0 °C at 760 mmHg

[ Melting Point ]:
-46ºC

[ Molecular Formula ]:
C6H10O4

[ Molecular Weight ]:
146.141

[ Flash Point ]:
76.1±0.0 °C

[ Exact Mass ]:
146.057907

[ PSA ]:
52.60000

[ LogP ]:
-0.01

[ Vapour Pressure ]:
1.3±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.409

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2917190090

Synthetic Route

Precursor & DownStream

Precursor

  • Dimethyl malonate
  • methyl iodide
  • dimethyl 2-(trifluoromethyl)propanedioate
  • Formaldehyde
  • Methanol
  • acrylic acid methyl ester
  • Methyl methacrylate
  • (Brommethyl)methylmalonsaeure-dimethylester
  • Dimethyl sulfate
  • 2-methylpropanedioyl dichloride

DownStream

  • Phenyl ethyl ketone
  • dimethyl 2-(chloromethyl)propanedioate
  • 3-Phenylpentanedioic acid
  • Methylmalonic acid
  • (2R)-3-methoxy-2-methyl-2-(2-nitrophenoxy)-3-oxopropanoate
  • dimethyl 2-methyl-2-(2-nitrophenoxy)propanedioate
  • 1,1,2,2-Ethenetetracarboxylicacid, 1,1,2,2-tetramethyl ester
  • dimethyl 2,2-dimethoxypropanedioate
  • Dimethyl isopropylmalonate

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Microwave-enhanced Pd (0)/acetic acid catalyzed allylation reactions of C, N, and O -pronucleophiles with alkynes. Patil NT, et al.

Tetrahedron Lett. 45(46) , 8497-99, (2004)


More Articles


Related Compounds

  • sodium dimethyl methylmalonate
  • lithium dimethyl methylmalonate
  • dimethyl 2-bromo-2-methylmalonate
  • dimethyl 2-(3-bromoallyl)-2-methylmalonate
  • dimethyl 2-(bromo(phenyl)methyl)-2-methylmalonate
  • dimethyl 2-[(tert-butoxycarbonyl)amino]-2-methylmalonate
  • 1-(1-ethoxy-4-propylcyclohexyl)-N-methylmethanamine
  • N-benzyl-N-(prop-2-en-1-yl)ethenesulfonamide
  • Cycloheptanemethanamine, 1-(cyclopropylmethoxy)-N-ethyl-
  • Carbamic acid, N-[2-[(methoxyamino)carbonyl]-3-methylphenyl]-, 1,1-dimethylethyl ester
  • N1-(6-methoxypyrimidin-4-yl)ethane-1,2-diamine
  • 1H,1'H-[2,2'-Biimidazole]-4,4',5,5'-tetracarboxylic acid
  • 1-(Bromomethyl)-1-(2-methoxyethoxy)-4-methylcyclohexane
  • (2R,3R)-2-hydroxy-3-[(Z)-3-(4-hydroxyphenyl)prop-2-enoyl]oxybutanedioic acid
  • 1-(Bromomethyl)-4-ethyl-1-(2-methoxyethoxy)cyclohexane
  • 1,3-Dimethyl-5-nitroso-6-[(2-phenylethyl)amino]-2,4(1H,3H)-pyrimidinedione
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