Ethyl methylmalonate

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Names

[ CAS No. ]:
609-08-5

[ Name ]:
Ethyl methylmalonate

[Synonym ]:
Ethyl methylmalonate
Propanedioic acid, 2-methyl-, diethyl ester
Propanedioic acid, methyl-, diethyl ester
MFCD00009162
Ethyl methylmalonate (VAN)
diethyl 2-methylpropanedioate
diethyl 2-methylmalonate
EINECS 210-175-7
Diethyl methylmalonate
Diethyl ethanedicarboxylate
Malonic acid, methyl-, diethyl ester (8CI)
Malonic acid, methyl-, diethyl ester
Diethylmethylmalonate

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
204.4±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C8H14O4

[ Molecular Weight ]:
174.194

[ Flash Point ]:
76.7±0.0 °C

[ Exact Mass ]:
174.089203

[ PSA ]:
52.60000

[ LogP ]:
1.05

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.421

[ Water Solubility ]:
immiscible

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S23-S24/25

[ WGK Germany ]:
3

[ HS Code ]:
2917190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Diethyl malonate
  • methyl iodide
  • diethylaminomethyl-methyl-malonic acid diethyl ester
  • 2-Allyl-2-MethylMalonic Acid Eiethyl Ester
  • Diethyl ether
  • diethyl 2-methyl-2-((phenylamino)methyl)malonate
  • diethyl α-(chloro)-methylmalonate
  • Methyl bromide
  • Diethyl (aminomethylene)malonate
  • diethyl 2-(hydroxymethylidene)propanedioate

DownStream

  • 2-hydroxy-3,5,6-trimethyl-1H-pyridin-4-one
  • Ethyl 2-methyl-4-pentenoate
  • 2-Amino-5-methylpyrimidine-4,6(1H,5H)-dione
  • Propanedioic acid,2-methyl-2-propyl-, 1,3-diethyl ester
  • oxazolinylbenzene
  • Ethyl benzoate
  • dibenzo[a,j]xanthylium perbromide
  • 2,3-dimethylcyclopentan-1-one
  • bis(2-thienyl) ketone
  • N,N-diethylthiophene-2-carboxamide

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

An erythromycin process improvement using the diethyl methylmalonate-responsive (Dmr) phenotype of the Saccharopolyspora erythraea mutB strain.

Appl. Microbiol. Biotechnol. 93(4) , 1575-83, (2012)

The Saccharopolyspora erythraea mutB knockout strain, FL2281, having a block in the methylmalonyl-CoA mutase reaction, was found to carry a diethyl methylmalonate-responsive (Dmr) phenotype in an oil-...

Abnormal Michael reaction. Reaction between 2-cyclohexenone and diethyl methylmalonate. Risinger GE and Haag WG.

J. Org. Chem. 38(20) , 3546-3647, (1973)

Alkylation reaction of poly (chloromethylstyrene) with malononitrile and diethyl methylmalonate using phase transfer catalysts. Nishikubo T, et al.

Makromol. Chem. 2(6-7) , 387-392, (1981)


More Articles

Related Compounds

  • methyl ethyl methylmalonate
  • t-butyl ethyl methylmalonate
  • ethyl 2-nitrophenyl methylmalonate
  • ethyl 2-methyl-2-carboethoxy-trans-4-hexenoate
  • ethyl 3-dimethyl(phenyl)silyl-2-ethoxycarbonyl-2-methyl-3-butenoate
  • ethyl 2-(2-trimethylsilylethynyl)benzoate
  • 3-[(1-{Furo[3,2-c]pyridin-4-yl}azetidin-3-yl)methoxy]pyridine
  • 5-fluoro-2-[1-(2-phenyl-2H-1,2,3-triazole-4-carbonyl)-octahydropyrrolo[3,4-b]pyrrol-5-yl]pyridine
  • N-(2-{[(4-fluorophenyl)methyl]sulfanyl}-4-oxo-3,4-dihydroquinazolin-3-yl)-5-oxo-1-phenylpyrrolidine-3-carboxamide
  • 1-{[2-(5-bromo-2-methoxyphenyl)-5-methyl-1,3-oxazol-4-yl]methyl}-4-(diethoxymethyl)-1H-1,2,3-triazole
  • N-{2-[5-(furan-2-yl)thiophen-2-yl]ethyl}-3-methanesulfonyl-2-oxoimidazolidine-1-carboxamide
  • 8-({3-[(2-ethyl-1H-imidazol-1-yl)methyl]azetidin-1-yl}sulfonyl)quinoline
  • Phenyl 2-methoxy-4-methyl-5-(propan-2-yl)benzene-1-sulfonate
  • 4-(Propan-2-yl)phenyl 4-bromo-2,5-dimethoxybenzene-1-sulfonate
  • 7-(4-{5-amino-1-[4-(trifluoromethyl)phenyl]-1H-1,2,3-triazole-4-carbonyl}piperazin-1-yl)-1-cyclopropyl-6-fluoro-4-oxo-1,4-dihydroquinoline-3-carboxylic acid
  • 1-[(1-{[1,1'-biphenyl]-4-carbonyl}azetidin-3-yl)methyl]-2-ethyl-1H-imidazole
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