L-leucine

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Names

[ CAS No. ]:
61-90-5

[ Name ]:
L-leucine

[Synonym ]:
MFCD00002617
Glusate
H-L-GLU-OH
Leucine
L-GLU
(l)-leucine
EINECS 200-522-0
H-GLU-OH
[14C]-L-(+)-Leucine
GLU
[14C]-L-Glutamic acid
L-2-Amino-4-methylpentanoic acid
(2S)-α-Leucine
GLUTACID
4-Methyl-L-norvaline
LEUCINE, L-
l-Leu
Leucinum
[3H]-L-Glutamic acid
Leucine (USP)
L-Leucine
S-leucine
QVYZ1Y1&1 &&L or S Form
2-Amino-4-methylpentanoic acid, (S)-
H-Leu-OH
(S)-2-amino-4-methyl-pentanoic acid
L-(+)-glutamic acid
(S)-(+)-Leucine
Aciglut
(S)-leucine
glutamic
L-(-)-2-Amino-4-methylpentanoic acid
LEU
Glutaton

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
225.8±23.0 °C at 760 mmHg

[ Melting Point ]:
286-288 ºC

[ Molecular Formula ]:
C6H13NO2

[ Molecular Weight ]:
131.173

[ Flash Point ]:
90.3±22.6 °C

[ Exact Mass ]:
131.094635

[ PSA ]:
63.32000

[ LogP ]:
0.73

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.463

[ Water Solubility ]:
22.4 g/L (20 C)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OH2850000
CHEMICAL NAME :
Leucine, L-
CAS REGISTRY NUMBER :
61-90-5
LAST UPDATED :
199706
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C6-H13-N-O2
MOLECULAR WEIGHT :
131.20
WISWESSER LINE NOTATION :
QVYZ1Y1&1 -L

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5379 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - body temperature decrease
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2620 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
138 gm/kg
SEX/DURATION :
female 5-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - other measures of fertility Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
90 mg/kg
SEX/DURATION :
female 1-6 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - other developmental abnormalities
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
90 mg/kg
SEX/DURATION :
female 1-6 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - body wall
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
90 mg/kg
SEX/DURATION :
female 1-6 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
60 mg/kg
SEX/DURATION :
female 6-9 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - Central Nervous System Reproductive - Specific Developmental Abnormalities - eye/ear Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
60 mg/kg
SEX/DURATION :
female 6-9 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Specific Developmental Abnormalities - urogenital system

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
10 mg/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 372,75,1996 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81818 No. of Facilities: 53 (estimated) No. of Industries: 1 No. of Occupations: 3 No. of Employees: 750 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81818 No. of Facilities: 1037 (estimated) No. of Industries: 4 No. of Occupations: 18 No. of Employees: 21979 (estimated) No. of Female Employees: 16153 (estimated)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
OH2850000

[ HS Code ]:
29224995

Synthetic Route

Precursor & DownStream

Precursor

  • 2-Amino-4-methylpentanoic acid
  • 4-methyl-2-oxopentanoate
  • Poc-Leu-OH
  • D,L-Leu(OBn)*HCl
  • rac-(R*)-2-Isobutylglycine ethyl ester
  • phenylmethyl (4S)-4-(2-methylpropyl)-5-oxo-1,3-oxazolidine-3-carboxylate
  • H-Leu-OBzl.TosOH

DownStream

  • H-D-Phg-Leu-OH
  • PTH-leucine
  • Z-MeLeu-OH
  • H-Phe-Leu-OH
  • Cyclo(-Phe-Phe)
  • H-Ala-Leu-OH
  • Z-Leu-OH.DCHA
  • Boc-N-methyl-L-leucine
  • Leu-Leu
  • H-Val-Val-OH

Customs

[ HS Code ]: 2922499990

[ Summary ]:
HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • L-Leucine
  • L-Leucine-d3
  • l-leucine-d7
  • L-Leucine HCl
  • L-Leucine-15N
  • L-Leucine-d10
  • (5-Amino-2-pyridinyl)(3-hydroxy-1-azetidinyl)methanone
  • 3-hydroxy-2-(1H-indol-3-yl)-2-Cyclohexen-1-one
  • 1-Chloro-3-fluoro-5-(2-nitroethyl)-benzene
  • 1a(2)-[6-(3-Methyl-1,2,4-thiadiazol-5-yl)-3-pyridazinyl]spiro[2H-1-benzopyran-2,3a(2)-pyrrolidin]-4(3H)-one
  • ethyl 4-(1H-indol-3-yl)-3-oxopiperidine-1-carboxylate
  • 2-Cyclopropyl-1-(pyridin-2-yl)ethan-1-one
  • 2-Cyclopropyl-1-(pyridin-3-yl)ethan-1-one
  • 2-Cyclopropyl-1-(pyrimidin-2-yl)ethan-1-amine
  • 1-phenyl-4-(3-(1-phenyl-3-propyl-1H-pyrazol-5-yl)propyl)piperazine
  • 3-[(2-Bromophenyl)sulfanyl]-2-methylcyclopentan-1-one
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