Benzenamine,N,2-dimethyl-

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Names

[ CAS No. ]:
611-21-2

[ Name ]:
Benzenamine,N,2-dimethyl-

[Synonym ]:
MFCD00025627
N,2-dimethylaniline
EINECS 210-260-9

Chemical & Physical Properties

[ Density]:
0.97

[ Boiling Point ]:
207 °C

[ Molecular Formula ]:
C8H11N

[ Molecular Weight ]:
121.18000

[ Flash Point ]:
79.4 °C

[ Exact Mass ]:
121.08900

[ PSA ]:
12.03000

[ LogP ]:
2.10970

[ Index of Refraction ]:
1.562-1.565

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H331-H373-H412

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R52/53

[ Safety Phrases ]:
S61-S45-S36/37-S28A-S28

[ RIDADR ]:
1711

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1(a)

[ HS Code ]:
2921430090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • N,N,2-Trimethylaniline
  • 1-(azidomethyl)-2-methylbenzene(SALTDATA: FREE)
  • Mercaptoacetic acid
  • Formamide,N-(2-methylphenyl)-
  • Dimethyl sulfate
  • O-ACETOTOLUIDIDE
  • 2-Bromotoluene
  • methylamine

DownStream

  • 4-Bromo-N,2-dimethylaniline
  • Indole
  • o-Toluidine
  • 1-Methyl-2-phenylindole
  • 2,4-Xylidine
  • 1,2-Dimethylindole
  • N,N,2-Trimethylaniline
  • 2,3-Dihydro-1-methylindol-2-one
  • 4-Methylamino-3-methylbenzaldehyde
  • (2-Ethylphenyl)methylamine

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Separation of isomeric amines with ion mobility spectrometry.

Talanta 132 , 889-93, (2015)

Eight selected isomeric amines were ionized using atmospheric pressure chemical ionization and atmospheric pressure photoionization producing a protonated molecule [M+H](+) for each amine. The mobilit...

Carbon dioxide: a reagent for the simultaneous protection of nucleophilic centers and the activation of alternative locations to electrophilic attack. XVI, A novel synthetic method for the side-chain functionalization of N-methyl-o-toluidine and for the preparation of 2-substituted N-methylindoles. Katritzky AR, et al.

Heterocycles 30(1) , 407-14, (1990)

A Practical Synthetic Method for N-Methyl-o-Toluidine. Katritzky AR and Akutagawa K.

Org. Prep. Proced. Int. 21(3) , 340-341, (1989)


More Articles

Related Compounds

  • Benzenamine,N,2-dimethyl-4-(1-methylethyl)
  • Benzenamine,N,2-dimethyl-5-(1-methylethyl)-
  • Benzenamine, N,2-dimethyl-4-(1-piperidinylmethyl)-
  • N,2-Dimethyl-3-nitroaniline
  • N,2-Dimethyl-4-nitroaniline
  • N,2-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
  • 4-(3-chlorophenyl)-N-{2-[(4-fluorobenzyl)amino]-2-oxoethyl}piperazine-1-carboxamide
  • 3-(2-(4-(4-Chlorophenyl)-4-hydroxypiperidin-1-yl)-2-oxoethyl)-1,3-diazaspiro[4.4]nonane-2,4-dione
  • methyl N-{3-[6-(benzyloxy)-1H-indol-1-yl]propanoyl}glycinate
  • 2-(3-oxo-3,5,7,8-tetrahydro-2H-thiopyrano[4,3-c]pyridazin-2-yl)-N-(4,5,6,7-tetrahydro-1,3-benzothiazol-2-yl)acetamide
  • 2-[3-(3,4-dimethoxyphenyl)-6-oxopyridazin-1(6H)-yl]-N-(1-methyl-1H-indol-4-yl)acetamide
  • 2'-(2-methoxyethyl)-4'-[(4-methylpiperidin-1-yl)carbonyl]-2'H-spiro[cyclopentane-1,3'-isoquinolin]-1'(4'H)-one
  • C19H18F4N4O2
  • 3-(6,8-dimethyl-[1,2,4]triazolo[4,3-b]pyridazin-7-yl)-N-(5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-2-yl)propanamide
  • 2-[2-(8-fluoro-1,3,4,5-tetrahydro-2H-pyrido[4,3-b]indol-2-yl)-2-oxoethyl]-2,5,6,7,8,9-hexahydro-3H-cyclohepta[c]pyridazin-3-one
  • N-(1H-indol-4-yl)-2-[2-(4-methoxyphenyl)-1,3-thiazol-4-yl]acetamide
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