Trichothec-9-ene-3,4,15-triol, 12, 13-epoxy-, 3,15-diacetate, (3.alpha.,4.beta.)-

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Names

[ Name ]:
Trichothec-9-ene-3,4,15-triol, 12, 13-epoxy-, 3,15-diacetate, (3.alpha.,4.beta.)-

[Synonym ]:
3,14-dithia-1,16-hexadecanediol
3,15-diacetoxyscirpenol
Eulip
2,2'-decane-1,10-diylbissulfanyl-bis-ethanol
Tiaden
3,15-Diacetoxyscirpen-4-ol
LL 1558
1,16-dihydroxy-3,14-dithiahexadecane
Fonlipol
TIADENOL
Fonilap
Thiadenol

Chemical & Physical Properties

[ Density]:
1.31g/cm3

[ Boiling Point ]:
472ºC at 760 mmHg

[ Molecular Formula ]:
C₁₉H₂₆O₇

[ Molecular Weight ]:
366.40600

[ Flash Point ]:
163.1ºC

[ Exact Mass ]:
366.16800

[ PSA ]:
94.59000

[ LogP ]:
1.12490

[ Index of Refraction ]:
1.56

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

((2S,3R,4S,5S,5aR,9aR)-3-acetoxy-4-hydroxy-5,8-dimethyl-10-methylene-2,3,4,5,7,9a-hexahydro-2,5-methanobenzo[b]oxepin-5a(6H)-yl)methyl acetate
(6R,7S,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-9-((1R)-4-hydroxy-1-(hydroxymethyl)-4-methylcyclohex-2-en-1-yl)-9-methyl-1,4-dioxaspiro[4.4]nonane-6,7-diol
((2'R,3'S,4'S,5'S,5a'R,9a'R)-4'-((tert-butyldimethylsilyl)oxy)-3'-hydroxy-5',8'-dimethyl-2',3',4',5',7',9a'-hexahydrospiro[[1,3]dioxolane-2,10'-[2,5]methanobenzo[b]oxepin]-5a'(6'H)-yl)methyl acetate
((1R)-1-((6S,7S,8S,9R)-7-((tert-butyldimethylsilyl)oxy)-8,9-dihydroxy-6-methyl-1,4-dioxaspiro[4.4]nonan-6-yl)-4-hydroxy-4-methylcyclohexan-1-yl)methyl acetate
(1S,5S,7R,8S)-7-(benzyloxy)-8-((tert-butyldimethylsilyl)oxy)-4-(hydroxymethylene)-5-methyl-2-oxaspiro[bicyclo[3.2.1]octane-6,2'-[1,3]dioxolan]-3-one
(1S,5S,7R,8S)-7-(benzyloxy)-8-((tert-butyldimethylsilyl)oxy)-4-((dimethylamino)methylene)-5-methyl-2-oxaspiro[bicyclo[3.2.1]octane-6,2'-[1,3]dioxolan]-3-one
((2'R,3'S,4'S,5'S,5a'R,9a'R)-3'-acetoxy-4'-((tert-butyldimethylsilyl)oxy)-5',8'-dimethyl-2',3',4',5',7',9a'-hexahydrospiro[[1,3]dioxolane-2,10'-[2,5]methanobenzo[b]oxepin]-5a'(6'H)-yl)methyl acetate
(1S,1'S,5'S,6'R,8'S)-6'-(benzyloxy)-8'-((tert-butyldimethylsilyl)oxy)-1'-methyl-4'-oxadispiro[cyclohexane-1,2'-bicyclo[3.2.1]octane-7',2''-[1,3]dioxolan]-2-ene-3',4-dione
(1S,1'S,5'S,6'R,8'S)-6'-(benzyloxy)-8'-((tert-butyldimethylsilyl)oxy)-4-hydroxy-1',4-dimethyl-4'-oxadispiro[cyclohexane-1,2'-bicyclo[3.2.1]octane-7',2''-[1,3]dioxolan]-2-en-3'-one
(1S,4R,5S,7R,8S)-7-(benzyloxy)-8-((tert-butyldimethylsilyl)oxy)-5-methyl-3-oxo-4-(3-oxobutyl)-2-oxaspiro[bicyclo[3.2.1]octane-6,2'-[1,3]dioxolane]-4-carbaldehyde