2-Amino-1-phenylethanone

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Names

[ CAS No. ]:
613-89-8

[ Name ]:
2-Amino-1-phenylethanone

[Synonym ]:
2-Acetylaniline
2-aminoacetophenone hydrochloride
a-Aminoacetophenone
Ethanone, 2-amino-1-phenyl-
ACETOPHENONE,2-AMINO
Ethanone, 1-(2-aminophenyl)-
w-Aminoacetophenone
2'-Amonioacetophenone
Phenacylamine
1-(2-Aminophenyl)ethanone
phenylcarbonylmethylamine
2-Amino-1-phenylethanone
o-Acetylaniline
2-Amino-1-phenylethan-1-one
o-Aminoacetophenone
2`-Aminoacetophenone
2-Aminoecetophenone
2-amino-1-phenyl-ethanone
2-amino-acetophenone
ortho-Aminoacetophenone

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
247.3±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C8H9NO

[ Molecular Weight ]:
135.163

[ Flash Point ]:
103.4±22.6 °C

[ Exact Mass ]:
135.068420

[ PSA ]:
43.09000

[ LogP ]:
0.81

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.552

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AM5775000
CHEMICAL NAME :
Acetophenone, 2-amino-
CAS REGISTRY NUMBER :
613-89-8
BEILSTEIN REFERENCE NO. :
0507952
LAST UPDATED :
199709
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C8-H9-N-O
MOLECULAR WEIGHT :
135.18
WISWESSER LINE NOTATION :
ZR BV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2000 mg/kg/7W-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Blood - leukemia
REFERENCE :
PGPKA8 Problemy Gematologii i Perelivaniia Krovi. Problems of Hematology and Blood Transfusion. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1956- Volume(issue)/page/year: 14,12,1969
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
1480 mg/kg/13W-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Liver - angiosarcoma Reproductive - Tumorigenic effects - uterine tumors
REFERENCE :
BEXBAN Bulletin of Experimental Biology and Medicine (English Translation). Translation of BEBMAE. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) V.41- 1956- Volume(issue)/page/year: 84,1156,1977
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - hamster
DOSE/DURATION :
1600 mg/kg/10W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Endocrine - adrenal cortex tumors Endocrine - thyroid tumors
REFERENCE :
VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 25(6),81,1979
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1600 mg/kg/8W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Kidney, Ureter, Bladder - tumors
REFERENCE :
VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 22(6),47,1976

Safety Information

[ HS Code ]:
2922399090

Synthetic Route

Precursor & DownStream

Precursor

  • Aminoform
  • 2-Bromoacetophenone
  • 2-azido-1-phenylethanone
  • Benzoic anhydride
  • a-Oxobenzeneacetaldehyde Aldoxime
  • Methyl 5-phenyl-1,3-oxazole-4-carboxylate
  • Benzoyl chloride
  • (E)-1,1-dimethyl-2-(1-phenyleth-1-ylidene)hydrazine
  • methyl iodide
  • Benzoyl cyanide

DownStream

  • 2-Amino-1-phenylethanone hydrochloride
  • 5-ethyl-6-methyl-3-[(5-phenyl-1,3-oxazol-2-yl)methylamino]-1H-pyridin-2-one
  • 3-Methyl-1H-indazole
  • 1-Allyl-1H-indole-2,3-dione
  • 4-Phenylimidazole-2-thiol
  • phenylethanolamine
  • 5-PHENYL-2-(4-PYRIDYL)OXAZOLE
  • 4(1H)-Quinolinone
  • N-phenacylpyridine-3-carboxamide
  • 5-phenyl-2-(2-phenylquinolin-4-yl)-1,3-oxazole

Customs

[ HS Code ]: 2922399090

[ Summary ]:
2922399090 other amino-aldehydes, amino-ketones and amino-quinones, other than those containing more than one kind of oxygen function; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%


Related Compounds

  • 2-amino-1-phenylethanone,hydrobromide
  • 2-amino-1-phenylethanone hydrochloride
  • 2-Amino-1-phenylethanone hydrochloride
  • 2-amino-1-morpholin-4-yl-2-phenylethanone
  • 2-amino-2-(4-methylphenyl)-1-phenylethanone
  • 2-Amino-1-butanol
  • Ethyl 3-bromo-2-cyano-5-fluorobenzoate
  • 3-(Azetidin-3-yl)-5-chloro-2-fluoropyridine
  • Ethyl I+/-,I(3)-dimethylbenzenebutanoate
  • Ethyl 4-bromo-2-cyano-6-fluorobenzoate
  • Ethyl 4-bromo-5-cyano-2-fluorobenzoate
  • 4-(3-Chloro-2,5-dioxo-1-pyrrolidinyl)benzoic acid
  • 8-(2-Propylfuran-3-carbonyl)-1-oxa-8-azaspiro[5.5]undecane-7-carbonitrile
  • 3-(1-(cyclohexylmethyl)-1H-indazole-3-carboxamido)-2,2-dimethylsuccinicacid
  • N-(1-amino-4-hydroxy-3,3-dimethyl-1-oxobutan-2-yl)-1-((4-hydroxycyclohexyl)methyl)-1h-indazole-3-carboxamide
  • (S)-2-Amino-N-((S)-2,6-dioxopiperidin-3-yl)-3-phenylpropanamide
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