2-Nitroacetophenone

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Names

[ CAS No. ]:
614-21-1

[ Name ]:
2-Nitroacetophenone

[Synonym ]:
α-Nitroacetophenone
2-Nitro-1-phenylethan-1-one
MFCD00010218
2-Nitroacetophenone
WN1VR
Ethanone, 2-nitro-1-phenyl-
2-Nitro-1-phenylethanone
Benzoylnitromethane
2-Nitro-1-phenylethanon

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
298.6±23.0 °C at 760 mmHg

[ Melting Point ]:
105-107ºC

[ Molecular Formula ]:
C8H7NO3

[ Molecular Weight ]:
165.146

[ Flash Point ]:
146.9±15.4 °C

[ Exact Mass ]:
165.042587

[ PSA ]:
62.89000

[ LogP ]:
1.68

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.545

[ Storage condition ]:
Refrigerator (+4°C)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2914700090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants.

J. Org. Chem. 62(23) , 8162-8170, (1997)

The replacement of a hydrogen in nitromethane and in phenylnitromethane by the PhCO group has a strong acidifying effect, i.e., PhCOCH(2)NO(2), 5, is 5.8, 6.6, and 8.6 pK(a) units more acidic than CH(...


More Articles

Related Compounds

  • 2-Nitroacetophenone
  • 2-nitroacetophenone oxime
  • 2-Bromo-2-nitroacetophenone
  • 5-methyl-2-nitroacetophenone
  • 4-methyl-2-nitroacetophenone
  • 4'-methyl-2-nitroacetophenone
  • N-(1-((1R,3R,4R,6S,7S)-1-((Tert-butyldiphenylsilyloxy)methyl)-7-hydroxy-6-methyl-2,5-dioxabicyclo[2.2.1]heptan-3-YL)-5-methyl-2-oxo-1,2-dihydropyrimidin-4-YL)benzamide
  • 1-(But-3-yn-1-yl)-3-ethylurea
  • N-(1-((1R,3R,4R,6S,7S)-7-Hydroxy-1-(hydroxymethyl)-6-methyl-2,5-dioxabicyclo[2.2.1]heptan-3-YL)-5-methyl-2-oxo-1,2-dihydropyrimidin-4-YL)benzamide
  • (3aR,4R,5R,6aS)-5-hydroxy-2-oxohexahydro-2H-cyclopenta[b]furan-4-carboxylic acid
  • 3-(4-Bromo-3-methylphenoxy)piperidine
  • N-(1-cyanocyclohexyl)-N-methyl-2-({5-oxo-4-[(oxolan-2-yl)methyl]-4,5-dihydro-1H-1,2,4-triazol-3-yl}sulfanyl)acetamide
  • N-(1-Cyanocyclohexyl)-2-[1-(3-methylphenyl)tetrazol-5-yl]sulfanylpropanamide
  • 1-(5-Ethoxy-3-pyridinyl)ethanone
  • N-[2-(diethylamino)ethyl]-2-[4-(2-methylpropyl)phenyl]propanamide
  • 3-(2-Aminobenzyl)-7-hydroxy-4-methyl-2-oxo-2h-1-benzopyran
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