2-Chloro-4-methylaniline

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Names

[ CAS No. ]:
615-65-6

[ Name ]:
2-Chloro-4-methylaniline

[Synonym ]:
2-Chloro-4-methylani
2-CHLORO-P-TOLUIDINE
p-Toluidine,2-chloro
2-CHLORO-PARA-TOLUIDINE
2-chlor-4-toluidine
2-CHLORO-4-TOLUIDINE
Benzenamine, 2-chloro-4-methyl-
2-Chlor-4-toluidin
1-amino-2chloro-4-methylbenzene
2-chloro-4-methyl-aniline
4-amino-5-chlorotoluene
2-Chloro-4-methylaniline
2-chloro-p-toluidin
MFCD00007666
EINECS 210-440-7
2-chloro-4-methylbenzeneamine
2-chloro-4-methylphenylamine
Chloro-p-toluidine
3-CHLORO-4-AMINOTOLUENE
4-AMINO-3-CHLOROTOLUENE

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
222.3±20.0 °C at 760 mmHg

[ Melting Point ]:
7 °C(lit.)

[ Molecular Formula ]:
C₇H₈ClN

[ Molecular Weight ]:
141.598

[ Flash Point ]:
99.4±0.0 °C

[ Exact Mass ]:
141.034531

[ PSA ]:
26.02000

[ LogP ]:
2.37

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.585

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XU5110000

CHEMICAL NAME :: p-Toluidine, 2-chloro-

CAS REGISTRY NUMBER :: 615-65-6

BEILSTEIN REFERENCE NO. :: 0774514

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C7-H8-Cl-N

MOLECULAR WEIGHT :: 141.61

WISWESSER LINE NOTATION :: ZR BG D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

MUTATION DATA

TYPE OF TEST :: Unscheduled DNA synthesis

TEST SYSTEM :: Rodent - rat Liver

DOSE/DURATION :: 100 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 206,183,1988

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312 + H332-H315-H318-H412

[ Precautionary Statements ]:
P273-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S36/37-S37/39-S26

[ RIDADR ]:
UN 3429 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
XU5110000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2921430090

Precursor & DownStream

Precursor

3-Chloro-4-nitrotoluene
4'-Methylacetanilide
4-Nitrotoluene
Acetamide,N-(2-chloro-4-methylphenyl)-
4-nitrosotoluene
4-(HYDROXYAMINO)TOLUENE
3-Chlorotoluene
Benzenamine,4-chloro-2-methyl-5-nitro-
acetic acid-(2,4,N-trichloro-anilide)
p-Toluidine

DownStream

2-Chloro-4-methylbenzaldehyde
1-Bromo-3-chloro-5-methylbenzene
3-Chloro-4-nitrotoluene
(2-Chloro-4-methylphenyl)hydrazine
2,4,6-Trichlorobenzoyl chloride
Acetamide,N-(2-chloro-4-methylphenyl)-
3,4-Dichlorotoluene
2-Chloro-4-methylbenzonitrile
2-Chloro-4-methylbenzoic acid
2-chloro-4-methylphenyl isothiocyanate

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

A method based on microextraction by packed sorbent-programmed temperature vaporizer-fast gas chromatography-mass spectrometry for the determination of aromatic amines in environmental water samples.

Anal. Bioanal. Chem 404(6-7) , 2007-15, (2012)

We report a sensitive method for the determination of 15 aromatic amines in environmental water samples. They have been included in the list of priority pollutants in surface water by the European Uni...

Fully automated on-line supported liquid membrane-liquid chromatographic determination of aniline derivates in environmental waters. Norberg J, et al.

Chromatographia 46(9-10) , 483-488, (1997)

2-Chloro-4-methylaniline
N-(tert.-butyloxycarbonyl)-2-chloro-4-methylaniline
2-chloro-4-methoxy-N-methylaniline
2-Chloro-4-cyclopropyl-6-methylaniline
2-Chloro-4-iodo-5-methylaniline
2-Chloro-4-nitro-N-methylaniline
Tert-butyl 4-(3-amino-2-chloro-5-cyanophenyl)-3-oxopiperazine-1-carboxylate
(3R)-1-(2-bromo-4-methylbenzoyl)pyrrolidin-3-ol
Tert-butyl 2-(3-amino-2-chloro-5-cyanophenyl)morpholine-4-carboxylate
Methyl 2-cyclopropyl-1-naphthoate
6-Fluoro-1-phenyl-1H-indazol-7-amine
5-Pyrimidinepropanoic acid, 6-amino-4-ethyl-1,2-dihydro-2-thioxo-
2-(2-Chloro-4,5-dimethoxyphenyl)propan-2-ol
4-(3-Phenylimidazol-4-yl)piperidine
6-Chloro-8-methoxyimidazo[1,2-a]pyrazine-2-carboxylic acid
5-(Difluoromethyl)pyridine-3-sulfonyl chloride

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