Dimethyl itaconate

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Names

[ CAS No. ]:
617-52-7

[ Name ]:
Dimethyl itaconate

[Synonym ]:
MFCD00008446
BUTANEDIOIC ACID, METHYLENE-, DIMETHYL ESTER
EINECS 210-519-6
itaconic acid, dimethyl ester
Dimethyl-2-methylidenbutandioat
Dimethyl 2-methylenesuccinate
Butanedioic acid, 2-methylene-, dimethyl ester
dimethyl 2-methylidenebutanedioate
dimethyl itaconate
Succinic acid, methylene-, dimethyl ester

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
208.0±0.0 °C at 760 mmHg

[ Melting Point ]:
37-41 °C(lit.)

[ Molecular Formula ]:
C7H10O4

[ Molecular Weight ]:
158.15

[ Flash Point ]:
99.4±0.0 °C

[ Exact Mass ]:
158.057907

[ PSA ]:
52.60000

[ LogP ]:
1.36

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.429

[ Water Solubility ]:
slightly soluble

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • Itaconic acid
  • methyl iodide
  • nitromethane
  • Dimethyl fumarate
  • carbon monoxide
  • Itaconic acid diethyl ester
  • Dimethyl succinate

DownStream

  • Methyl 1-benzyl-5-oxo-3-pyrrolidinecarboxylate
  • Methyl 1-Methyl-2-oxopyrrolidine-4-carboxylate
  • 1-Benzyl-2-oxopyrrolidine-4-carboxylic acid
  • 1-methyl-5-oxo-pyrrolidine-3-carboxylic acid
  • Trimethyl trans-Aconitate
  • (S)-METHYL PYRROLIDINE-3-CARBOXYLATE
  • Methyl 5-oxopyrrolidine-3-carboxylate
  • 4-FORMYLPHENYLBORONICACID
  • dimethyl 2-(methoxymethyl)butanedioate
  • 5-oxo-1-(2-phenylethyl)pyrrolidine-3-carboxylic acid

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Electronic Effects in Asymmetric Catalysis: Structural Studies of Precatalysts and Intermediates in Rh-Catalyzed Hydrogenation of Dimethyl Itaconate and Acetamidocinnamic Acid Derivatives Using C(2)-Symmetric Diarylphosphinite Ligands.

J. Org. Chem. 64(10) , 3429-3447, (1999)

Enantioselectivity of Rh(I)-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives and dimethyl itaconate can be enhanced by the appropriate choice of substituents on the aromatic rings o...

Modification of poly (propylene) through grafting with dimethyl itaconate in solution. Yazdani-Pedram M, et al.

Macromol. Chem. Phys. 199(11) , 2495-2500, (1998)

Polymers with shape memory effect from renewable resources: crosslinking of polyesters based on isosorbide, itaconic acid and succinic acid. Goerz O and Ritter H.

Polym. Int. 62(5) , 709-712, (2013)


More Articles

Related Compounds

  • dimethyl itaconate
  • dimethyl-bis(2-methylpropyl)azanium,iodide
  • [dimethyl(phenyl)-λ5-arsanyl] thiohypobromite
  • [dimethyl(phenyl)-λ5-arsanyl] thiohypochlorite
  • dimethyl glutarate
  • dimethyl cyclopentane-1,1-dicarboxylate
  • 2-chloro-N-(5-ethyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)benzamide
  • N-(5-ethyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-3,4-dimethylbenzamide
  • N-(5-ethyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-2-methoxyacetamide
  • N-(5-ethyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-3,3-dimethylbutanamide
  • N-((3-methyl-1,2,4-oxadiazol-5-yl)methyl)-2-(2-oxobenzo[d]oxazol-3(2H)-yl)acetamide
  • N-(5-ethyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-[1,1'-biphenyl]-4-carboxamide
  • N8-Cyclopentyl-9-ethyl-9H-purine-6,8-diamine
  • N-(2-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl}ethyl)-4-methylbenzamide
  • 3-(5-(2-amino-1-methyl-1H-benzo[d]imidazol-4-yloxy)-1-oxoisoindolin-2-yl)propanoic acid
  • 4-{[4-(2-Fluoropyridine-4-carbonyl)piperazin-1-yl]methyl}benzonitrile
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