4-Methylbenzamide

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Names

[ CAS No. ]:
619-55-6

[ Name ]:
4-Methylbenzamide

[Synonym ]:
p-toluamide
p-Methylbenzamide
4-Methylbenzamide
EINECS 210-600-6
4-methylphenylformamide
MFCD00008002
Benzamide, 4-methyl-
4-Methylbenzolcarboxamid

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
270.4±19.0 °C at 760 mmHg

[ Melting Point ]:
159-162 °C

[ Molecular Formula ]:
C8H9NO

[ Molecular Weight ]:
135.163

[ Flash Point ]:
117.3±21.5 °C

[ Exact Mass ]:
135.068420

[ PSA ]:
43.09000

[ LogP ]:
1.20

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.556

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CV5570150
CHEMICAL NAME :
Benzamide, 4-methyl-
CAS REGISTRY NUMBER :
619-55-6
LAST UPDATED :
199709
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C8-H9-N-O
MOLECULAR WEIGHT :
135.18

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 28,335,1994

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
22-36

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
CV5570150

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • p-Tolualdehyde
  • carbon monoxide
  • 4-Iodotoluene
  • 4-Bromotoluene
  • p-Tolunitrile
  • 4-Methylbenzylamine
  • Benzaldehyde,4-methyl-, oxime
  • p-tolylmethanol
  • 4-methylbenzoyl azide
  • 4-Methylbenzoic acid

DownStream

  • [(4-methylbenzoyl)amino] N,N-diethylcarbamodithioate
  • p-tolylmethanol
  • 4-Methylbenzylamine
  • Benzoyl chloride
  • p-toluoyl chloride
  • Benzonitrile
  • p-Tolunitrile
  • N-benzoyl-4-methylbenzamide
  • benzoic acid
  • methyl p-toluate

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Alumina catalyzed transformations of O-(3-oxobutyl) urethanes. Reitz A, et al.

Tetrahedron Lett. 23(7) , 751-2, (1982)


More Articles

Related Compounds

  • 4-methylbenzamide oxime
  • 4-Methylbenzamide oxime
  • 3-iodo-4-methylbenzamide
  • 3-BROMO-4-METHYLBENZAMIDE
  • 2-bromo-4-methylbenzamide
  • N-bromo-4-methylbenzamide
  • 3-(3-Hydroxypropyl)-3,4-dihydropyrimidin-4-one
  • 8-(Pyridazin-3-yl)-8-azabicyclo[3.2.1]octan-3-ol
  • 4-[(6-Oxopyrimidin-1-yl)methyl]benzoic acid
  • 8-(Pyrimidin-4-yl)-8-azabicyclo[3.2.1]octan-3-ol
  • (1R,5S)-8-(pyridin-2-ylmethyl)-8-azabicyclo[3.2.1]octan-3-ol
  • 4-Chloro-2-cyclopropyl-5,6,7,8-tetrahydroquinazoline
  • 8-(3-Chloro-5-(trifluoromethyl)pyridin-2-yl)-8-azabicyclo[3.2.1]octan-3-ol
  • 8-(Thiazol-2-yl)-8-azabicyclo[3.2.1]octan-3-ol
  • 8-{[4-(Trifluoromethoxy)phenyl]methyl}-8-azabicyclo[3.2.1]octan-3-ol
  • 2-(2,4-Dimethyl-6-oxopyrimidin-1(6H)-yl)acetic acid
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