4-Iodobenzoic acid

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Names

[ CAS No. ]:
619-58-9

[ Name ]:
4-Iodobenzoic acid

[Synonym ]:
para-iodobenzoic acid
QVR DI
4-Iodobenzoic acid
p-Iodobenzenecarboxylic acid
4-Jodbenzoesaeure
Benzoic acid,4-iodo
4-Iodo-benzoic acid
4-HO2CC6H4I
Benzoic acid, 4-iodo-
p-Iodobenzoic Acid
p-iodobenzoic_acid
MFCD00002533
Benzoic acid, p-iodo-
EINECS 210-603-2
Benzoic acid,p-iodo

Chemical & Physical Properties

[ Density]:
2.0±0.1 g/cm3

[ Boiling Point ]:
318.5±25.0 °C at 760 mmHg

[ Melting Point ]:
270-273 °C(lit.)

[ Molecular Formula ]:
C₇H₅IO₂

[ Molecular Weight ]:
248.018

[ Flash Point ]:
146.4±23.2 °C

[ Exact Mass ]:
247.933411

[ PSA ]:
37.30000

[ LogP ]:
3.02

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.666

[ Storage condition ]:
Store at RT.

[ Water Solubility ]:
0.04 g/L (25 ºC)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DH2976000

CHEMICAL NAME :: Benzoic acid, p-iodo-

CAS REGISTRY NUMBER :: 619-58-9

BEILSTEIN REFERENCE NO. :: 1860232

LAST UPDATED :: 199709

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C7-H5-I-O2

MOLECULAR WEIGHT :: 248.02

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PHARAT Pharmazie. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1946- Volume(issue)/page/year: 12,415,1957

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DH2976000

[ HS Code ]:
29163900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Carbon dioxide
2-(4-iodophenyl)-5,5-dimethyl-1,3,2-dioxaborinane
p-Boronobenzoic acid
4-Aminobenzoic acid
carbon monoxide
4-Iodobenzenediazonium tetrafluoroborate
(4-iodophenyl)zinc(II) iodide
4-Iodotoluene
4-iodo-N,N-bis(pyridin-2-ylmethyl)benzamide

DownStream

Benzoic acid, 4-iodo-, 1-Methylethyl ester
4-FURAN-2-YL-BENZOIC ACID
2-Bromo-4'-iodoacetophenone
4'-Amino-4-biphenylcarboxylic acid
4-Octylbenzoic acid
2'-METHYL-[1,1'-BIPHENYL]-4-CARBOXYLIC ACID
4-(Trifluoromethyl)benzoyl chloride
4-(4-ETHYLPHENYL)BENZOIC ACID
4-Pyridin-4-yl-benzoic acid
4-Pyridin-3-yl-benzoic acid

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Nat. Commun. 5 , 3870, (2014)

The shape-controlled synthesis of nanoparticles was established in single-phase solutions by controlling growth directions of crystalline facets on seed nanocrystals kinetically; however, it was diffi...

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A facile and operationally convenient catalytic procedure for oxidative cleavage of alkenes is described. In situ formed [hydroxy(4-carboxyphenyl)iodonium]ion, 2, from the oxidation of 4-iodobenzoic a...