m-Chlorbenzyl chloride

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Names

[ CAS No. ]:
620-20-2

[ Name ]:
m-Chlorbenzyl chloride

[Synonym ]:
A,M-DICHLOROTOLUENE
meta-chlorobenzyl chloride
EINECS 210-629-4
m,α-Dichlorotoluene
m,a-Dichlorotoluene
m-Chlorbenzyl chloride
3-chloro-benzyl chloride
M-CHLOROBENZYL CHLORIDE
MFCD00000905
Toluene, m,α-dichloro-
3-chlorophenylmethyl chloride
MCBC
Benzene, 1-chloro-3- (chloromethyl)-
Benzene, 1-chloro-3-(chloromethyl)-
1-Chloro-3-(chloromethyl)benzene
3-Chlorobenzyl chlor
3-Chlorobenzyl chloride

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
213.7±15.0 °C at 760 mmHg

[ Melting Point ]:
69-71ºC

[ Molecular Formula ]:
C7H6Cl2

[ Molecular Weight ]:
161.029

[ Flash Point ]:
98.9±0.0 °C

[ Exact Mass ]:
159.984650

[ LogP ]:
3.08

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.547

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/21/22;R36;R43;R51/53

[ Safety Phrases ]:
S26-S36/37/39-S45-S61-S14C

[ RIDADR ]:
UN 2235 6.1/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Chlorobenzyl alcohol
  • 3-Chlorotoluene
  • Carbon tetrachloride
  • hepta-1,2,4-trien-6-yne
  • Sulfuryl chloride
  • 3-Bromotoluene
  • Benzoyl peroxide
  • (3-chlorophenyl)methylium
  • 1-(1-chloro-2,2,2-trifluoroethyl)-3,5-dimethylbenzene

DownStream

  • 3-[2-(3-CHLORO-PHENYL)-ETHYL]-PYRIDINE-2-CARBOXYLIC ACID TERT-BUTYLAMIDE
  • 2-[(3-chlorobenzyl)thio]ethanamine(SALTDATA: FREE)
  • Loratadine Impurity 2
  • Loratadine Impurity 18
  • N-Methyl Desloratadine
  • n-methyl-m-chlorobenzylamine
  • (3-Chlorobenzyl)hydrazine
  • 1-chloro-3-(phenoxymethyl)benzene
  • 2-[(3-chlorophenyl)methyl]phenol
  • 3-[2-(3-chlorophenyl)ethyl]pyridine-2-carboxylic acid,hydrochloride

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Cross-couplings between benzylic and aryl halides "on water": synthesis of diarylmethanes.

Chem. Commun. (Camb.) 46(4) , 562-4, (2010)

A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide...


More Articles

Related Compounds

  • m-Chlorbenzyl chloride
  • ethyl-(3-chloro-benzyl)-ether
  • 1-[(1E)-3-(4-Chlorophenyl)-3-oxo-1-propen-1-yl]-3-methylpyridiniu m chloride
  • 4-Methyl-1-[2-(2-methyl-1,3-benzodioxol-2-yl)ethyl]piperazin-1-iu m chloride
  • m-Benzenedisulfonyl chloride
  • m-fluorophenylmercuric chloride