1-ADAMANTYLOXYCARBONYL FLUORIDE

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Names

[ CAS No. ]:
62087-82-5

[ Name ]:
1-ADAMANTYLOXYCARBONYL FLUORIDE

[Synonym ]:
MFCD00074772
1-Adamantyl fluoroformate
EINECS 263-400-6
Adamantyl fluoroformate
1-ADAMANTYLOXYCARBONYL FLUORIDE

Chemical & Physical Properties

[ Density]:
1.2g/cm3

[ Boiling Point ]:
253.2ºC at 760 mmHg

[ Melting Point ]:
30-32ºC(lit.)

[ Molecular Formula ]:
C11H15FO2

[ Molecular Weight ]:
198.23400

[ Flash Point ]:
192 °F

[ Exact Mass ]:
198.10600

[ PSA ]:
26.30000

[ LogP ]:
3.06130

[ Index of Refraction ]:
1.503

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 2921 8/PG 1

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Chloroethyl 1-Adamantyl Carbonate
  • Adamantan-1-ol
  • Fluorotrichloromethane

DownStream

  • 1-Fluoroadamantane
  • Adamantan-1-ol
  • 1-(2,2,2-trifluoroethoxy)adamantane
  • 1-((1,1,1,3,3,3-hexafluoropropan-2-yl)oxy)adamantane
  • 1-Adamantyl ethyl ether
  • 1-Adamantyl ethyl carbonate
  • 1-adamantyl methyl ether
  • 1-adamantyl methyl carbonate
  • 1-adamantyl-isopropyl ether

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

[1-Adamanty fluoroformate, a useful reagent in peptide chemistry (author's transl)].

Hoppe. Seylers. Z. Physiol. Chem. 357 , 1647, (1976)

1-Adamantyl fluoroformate was prepared from 1-adamantol and fluorophosgene. The cristalline and stable fluoroformate was allowed to react with amino acids to give the corresponding 1-adamantyloxycarbo...

G.W. Kenner et al.

Tetrahedron 35 , 2767, (1979)

I.J. Galpin et al.

Tetrahedron 35 , 2771, (1979)


More Articles

Related Compounds

  • 1-nitrosotetrafluoroethanesulfonyl fluoride
  • 1-perfluoropropanesulfonyl fluoride
  • 1-fluoroglucopyranosyl fluoride
  • 1-bromoethenesulfonyl fluoride
  • 1-Pyrrolidinecarbonyl fluoride, 2,2-difluoro- (7CI,8CI)
  • 1-fluorosulfonyloxytetrafluoroethanesulfonyl fluoride
  • [(3-Fluorophenyl)methyl](2-methylpentyl)amine
  • (2S,3R,5S)-Methyl 3,5-dimethylpyrrolidine-2-carboxylate
  • 1-methyl-N-(pentafluorophenyl)-1H-pyrazol-4-amine
  • 4-{4-[1-(2-fluorophenyl)-1H-pyrazol-4-yl]pyrimidin-2-yl}-1-methylpiperazin-2-one
  • 4-Chloro-2-fluoro-6-iodoanisole
  • n-(1-(Furan-2-yl)propan-2-yl)-5-nitropyridin-2-amine
  • methyl 4-(5-fluoro-2-oxo-2,3-dihydro-1H-indol-3-yl)-5-(3-methoxyphenyl)-2-methyl-1H-pyrrole-3-carboxylate
  • 2-[2-(2-furyl)pyrimidin-5-yl]-7-methyl-1H-benzimidazole
  • (2S,2'S,5'R)-Lilac aldehyde
  • (R)-Methyl 2-hydroxy-2-(2-methoxyphenyl)acetate
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