m-Tolylacetic acid

Names

[ CAS No. ]:
621-36-3

[ Name ]:
m-Tolylacetic acid

[Synonym ]:
2-(3-methylphenyl)acetic acid
Benzeneacetic acid, 3-methyl-
MFCD00004340
EINECS 210-683-9
(3-Methylphenyl)acetic acid
M-Tolylacetic acid (MTAA)
3-Methylphenylacetic acid

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
275.5±9.0 °C at 760 mmHg

[ Melting Point ]:
64-66 °C(lit.)

[ Molecular Formula ]:
C₉H₁₀O₂

[ Molecular Weight ]:
150.174

[ Flash Point ]:
172.7±13.9 °C

[ Exact Mass ]:
150.068085

[ PSA ]:
37.30000

[ LogP ]:
1.97

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.546

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

carbon monoxide
3-Methyl-benzyl chloride
Ethyl meta-tolylacetate
1-(Brommethyl)-3-methylbenzol
N,N-diethyl-N-(3-methylbenzyl)ethanaminium chloride
3-Bromophenylacetic acid
Dimethylzinc
m-Xylene
3'-Methylacetophenone
2-diazonio-1-(3-methylphenyl)ethenolate

DownStream

3-[(3-methylphenyl)methylidene]-2-benzofuran-1-one
6-[2-(m-tolyl)acetyl]-4H-1,4-benzoxazin-3-one
5-methyl-3,4-dihydro-1H-naphthalen-2-one
Ethyl meta-tolylacetate
2-(2-Bromo-5-methylphenyl)acetic acid
(2-Iodo-5-methylphenyl)acetic acid
2-(3-Methylphenyl)ethanol
3-TOLYLACETALDEHYDE
3-Methylbenzyl isocyanate
Methyl 2-(m-tolyl)acetate

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

High-performance liquid chromatographic analysis on radial compression column of the neurotoxic tri-o-cresyl phosphate and metabolites.

Anal. Biochem. 135(2) , 296-303, (1983)

A method utilizing high-performance liquid chromatography (HPLC) has been developed for the analysis of tri-o-cresyl phosphate (TOCP) and its possible metabolites, o-cresyl dihydrogen phosphate, di-o-...

[Further studies on the metabolic behavior of some aromatic and hydroaromatic mono- and dicarboxylic acids].

Hoppe. Seylers. Z. Physiol. Chem. 310(1-2) , 37-43, (1958)