Benzene, azido-

Names

[ CAS No. ]:
622-37-7

[ Name ]:
Benzene, azido-

[Synonym ]:
phenylazoimide
phenylazide
triazobenzene
Azidobenzene
Benzene,triazo
diazobenzeneimide
diazoaminobenzene
diazoaniline
Azidobenzene solution
1-azidobenzene

Chemical & Physical Properties

[ Density]:
1.0860

[ Boiling Point ]:
212.39°C (rough estimate)

[ Melting Point ]:
-27.5°C

[ Molecular Formula ]:
C₆H₅N₃

[ Molecular Weight ]:
119.12400

[ Flash Point ]:
-12ºC

[ Exact Mass ]:
119.04800

[ PSA ]:
49.75000

[ LogP ]:
2.08116

[ Index of Refraction ]:
1.5589

[ Storage condition ]:
?20°C

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H373

[ Supplemental HS ]:
May form explosive peroxides.

[ Precautionary Statements ]:
P210

[ Hazard Codes ]:
F,Xn

[ Risk Phrases ]:
11-19-48/20/21/22-38

[ Safety Phrases ]:
16

[ RIDADR ]:
UN 2398 3 / PGII

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Iodobenzene
Phenylboronic acid
Bromobenzene
1-AZIDO-4-IODOBENZENE SOLUTION
1-Azido-3-iodobenzene solution
1-Azido-2-iodobenzene solution
Phenylhydrazine
1-nitroso-1-phenyl-3-(4-pyridylmethyl)-urea
benzenediazonium

DownStream

N-trimethylstannylaniline
4-[(2-chlorophenoxy)methyl]-1-phenyltriazole
5-[(2-chlorophenoxy)methyl]-1-phenyltriazole
1-PHENYL-1H-1,2,3-TRIAZOLE-4-CARBALDEHYDE
1-phenyl-1,2,3-triazole-5-carbaldehyde
1H-Isoindol-1-one,2,3-dihydro-2-phenyl-
4-Bromo-N-phenylaniline
2-Bromodiphenylamine
3-BROMODIPHENYLAMINE
N-(4-Fluorophenyl)aniline

Articles

Regioselective Sequential Modification of Chitosan via Azide-Alkyne Click Reaction: Synthesis, Characterization, and Antimicrobial Activity of Chitosan Derivatives and Nanoparticles.

PLoS ONE 10 , e0123084, (2015)

Recently, the attention of researchers has been drawn toward the synthesis of chitosan derivatives and their nanoparticles with enhanced antimicrobial activities. In this study, chitosan derivatives w...

An automated multiplex specific IgE assay system using a photoimmobilized microarray.

J. Biotechnol. 161(4) , 414-21, (2012)

An automated microarray diagnostic system for specific IgE using photoimmobilized allergen has been developed. Photoimmobilization is useful for preparing microarrays, where various types of biologica...

Inhibition of monoamine oxidase by phenyl azides.

J. Neurochem. 45(3) , 940-5, (1985)

We had previously shown that 4-fluoro-3-nitrophenyl azide (FNPA) is a competitive inhibitor of both types of monoamine oxidase (MAO) in the dark, but it is a preferential photoaffinity label for only ...